FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2312706227> ?p ?o ?g. }

• W2312706227 endingPage "6084" @default.
• W2312706227 startingPage "6080" @default.
• W2312706227 abstract "A series of new agostic (CH3···Rh) (π-allyl)-closo-rhodacarboranes (π-allyl = 1,1-dimethylallyl, 1,2-dimethylallyl, 1,1,2-trimethylallyl, 1,2,3-trimethylallyl), stable in the solid state, have been synthesized via one-pot reactions between the K+ salts of the [7-R-8-R′-7,8-nido-C2B9H10]− monoanions (1a, R = R′ = Me; 1b, R,R′ = μ-(o-xylylene); 1c, R,R′ = μ-(CH2)3) and the di-μ-chloro cyclooctene rhodium dimer [(η2-C8H14)4Rh2(μ-Cl)2] (2) in the presence of a 3-fold excess of the conjugated 1,3-dienes 2-methylbuta-1,3-diene (isoprene, 3), 2,3-dimethylbuta-1,3-diene (4), and 3-methylpenta-1,3-diene (5). The agostic structures of [3-{(1–3-η3)-1,1-dimethylallyl}-1,2-(CH3)2-3,1,2-closo-RhC2B9H9] (7a) and [3-{(1–3-η3)-1,1,2-trimethylallyl}-1,2-(CH3)2-3,1,2-closo-RhC2B9H9] (8a) have been unambiguously confirmed by single-crystal X-ray diffraction studies. Two of these π-allyl complexes prepared were evaluated for their efficacy in hydroformylation of the model alkenes under syngas (CO/H2) using supercritical carbon dioxide (scCO2) as the solvent, and both display excellent conversion and high regioselectivity in the formation of aldehyde products." @default.
• W2312706227 created "2016-06-24" @default.
• W2312706227 creator A5002044625 @default.
• W2312706227 creator A5004817483 @default.
• W2312706227 creator A5011357319 @default.
• W2312706227 creator A5016070811 @default.
• W2312706227 creator A5040023182 @default.
• W2312706227 creator A5046140968 @default.
• W2312706227 creator A5081870737 @default.
• W2312706227 creator A5082532445 @default.
• W2312706227 date "2012-08-10" @default.
• W2312706227 modified "2023-10-09" @default.
• W2312706227 title "New Acyclic (π-Allyl)<i>-closo</i>-rhodacarboranes with an Agostic CH₃···Rh Bonding Interaction That Operate as Unmodified Rhodium-Based Catalysts for Alkene Hydroformylation" @default.
• W2312706227 cites W1963572494 @default.
• W2312706227 cites W1968268108 @default.
• W2312706227 cites W1973714797 @default.
• W2312706227 cites W1975500584 @default.
• W2312706227 cites W1976178852 @default.
• W2312706227 cites W1979857603 @default.
• W2312706227 cites W1982486435 @default.
• W2312706227 cites W1984604898 @default.
• W2312706227 cites W2002525079 @default.
• W2312706227 cites W2003620147 @default.
• W2312706227 cites W2008647592 @default.
• W2312706227 cites W2009319044 @default.
• W2312706227 cites W2013308031 @default.
• W2312706227 cites W2014501280 @default.
• W2312706227 cites W2028059814 @default.
• W2312706227 cites W2029451609 @default.
• W2312706227 cites W2029695420 @default.
• W2312706227 cites W2056238197 @default.
• W2312706227 cites W2059376925 @default.
• W2312706227 cites W2068886693 @default.
• W2312706227 cites W2071827442 @default.
• W2312706227 cites W2072358117 @default.
• W2312706227 cites W2072869918 @default.
• W2312706227 cites W2075238951 @default.
• W2312706227 cites W2075981453 @default.
• W2312706227 cites W2089680572 @default.
• W2312706227 cites W2101754594 @default.
• W2312706227 cites W2118832358 @default.
• W2312706227 cites W2139858161 @default.
• W2312706227 cites W2140501678 @default.
• W2312706227 cites W2183357597 @default.
• W2312706227 cites W2316172226 @default.
• W2312706227 doi "https://doi.org/10.1021/om300432j" @default.
• W2312706227 hasPublicationYear "2012" @default.
• W2312706227 type Work @default.
• W2312706227 sameAs 2312706227 @default.
• W2312706227 citedByCount "15" @default.
• W2312706227 countsByYear W23127062272013 @default.
• W2312706227 countsByYear W23127062272014 @default.
• W2312706227 countsByYear W23127062272015 @default.
• W2312706227 countsByYear W23127062272016 @default.
• W2312706227 countsByYear W23127062272017 @default.
• W2312706227 countsByYear W23127062272018 @default.
• W2312706227 countsByYear W23127062272020 @default.
• W2312706227 countsByYear W23127062272023 @default.
• W2312706227 crossrefType "journal-article" @default.
• W2312706227 hasAuthorship W2312706227A5002044625 @default.
• W2312706227 hasAuthorship W2312706227A5004817483 @default.
• W2312706227 hasAuthorship W2312706227A5011357319 @default.
• W2312706227 hasAuthorship W2312706227A5016070811 @default.
• W2312706227 hasAuthorship W2312706227A5040023182 @default.
• W2312706227 hasAuthorship W2312706227A5046140968 @default.
• W2312706227 hasAuthorship W2312706227A5081870737 @default.
• W2312706227 hasAuthorship W2312706227A5082532445 @default.
• W2312706227 hasConcept C100805817 @default.
• W2312706227 hasConcept C137955730 @default.
• W2312706227 hasConcept C153914509 @default.
• W2312706227 hasConcept C155647269 @default.
• W2312706227 hasConcept C15920480 @default.
• W2312706227 hasConcept C161790260 @default.
• W2312706227 hasConcept C176933379 @default.
• W2312706227 hasConcept C178790620 @default.
• W2312706227 hasConcept C185592680 @default.
• W2312706227 hasConcept C188328357 @default.
• W2312706227 hasConcept C2776254738 @default.
• W2312706227 hasConcept C2778733088 @default.
• W2312706227 hasConcept C2780959689 @default.
• W2312706227 hasConcept C44228677 @default.
• W2312706227 hasConcept C521398313 @default.
• W2312706227 hasConcept C521977710 @default.
• W2312706227 hasConcept C544153396 @default.
• W2312706227 hasConcept C59759590 @default.
• W2312706227 hasConcept C71240020 @default.
• W2312706227 hasConceptScore W2312706227C100805817 @default.
• W2312706227 hasConceptScore W2312706227C137955730 @default.
• W2312706227 hasConceptScore W2312706227C153914509 @default.
• W2312706227 hasConceptScore W2312706227C155647269 @default.
• W2312706227 hasConceptScore W2312706227C15920480 @default.
• W2312706227 hasConceptScore W2312706227C161790260 @default.
• W2312706227 hasConceptScore W2312706227C176933379 @default.
• W2312706227 hasConceptScore W2312706227C178790620 @default.
• W2312706227 hasConceptScore W2312706227C185592680 @default.
• W2312706227 hasConceptScore W2312706227C188328357 @default.
• W2312706227 hasConceptScore W2312706227C2776254738 @default.
• W2312706227 hasConceptScore W2312706227C2778733088 @default.

• next