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- W2312807455 abstract "Photodimerization of 2-pyridones produces primarily a trans tricyclic product with a center of symmetry. Treatment of this product with chlorine leads to an amide nitrogen migration and formation of a chiral product with six stereogenic centers. We have explored the chemistry of this readily available product with the goal of producing a stereo-defined acyclic product and report here the preparation and crystal structure of a ten-carbon product rich with stereochemistry. Opening of two bridging lactams has proven to be difficult." @default.
- W2312807455 created "2016-06-24" @default.
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- W2312807455 date "2010-05-27" @default.
- W2312807455 modified "2023-10-01" @default.
- W2312807455 title "Unraveling the stereochemically rich 2-pyridone [4+4] photodimer" @default.
- W2312807455 doi "https://doi.org/10.3998/ark.5550190.0011.814" @default.
- W2312807455 hasPublicationYear "2010" @default.
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