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• W2312837375 endingPage "12140" @default.
• W2312837375 startingPage "12135" @default.
• W2312837375 abstract "Tripositive lanthanide and actinide ions, Ln3+ (Ln = La–Lu) and An3+ (An = Pu, Am, Cm), were transferred from solution to gas by electrospray ionization as Ln(L)33+ and An(L)33+ complexes, where L = tetramethyl-3-oxa-glutaramide (TMOGA). The fragmentation chemistry of the complexes was examined by collision-induced and electron transfer dissociation (CID and ETD). Protonated TMOGA, HL+, and Ln(L)(L–H)2+ are the major products upon CID of La(L)33+, Ce(L)33+, and Pr(L)33+, while Ln(L)23+ is increasingly pronounced beyond Pr. A C–Oether bond cleavage product appears upon CID of all Ln(L)33+; only for Eu(L)33+ is the divalent complex, Eu(L)22+, dominant. The CID patterns of Pu(L)33+, Am(L)33+, and Cm(L)33+ are similar to those of the Ln(L)33+ for the late Ln. A striking exception is the appearance of Pu(IV) products upon CID of Pu(L)33+, in accord with the relatively low Pu(IV)/Pu(III) reduction potential in solution. Minor divalent Ln(L)22+ and An(L)22+ were produced for all Ln and An; with the exception of Eu(L)22+ these complexes form adducts with O2, presumably producing superoxides in which the trivalent oxidation state is recovered. ETD of Ln(L)33+ and An(L)33+ reveals behavior which parallels that of the Ln3+ and An3+ ions in solution. A C–Oether bond cleavage product, in which the trivalent oxidation state is preserved, appeared for all complexes; charge reduction products, Ln(L)22+ and Ln(L)32+, appear only for Sm, Eu, and Yb, which have stable divalent oxidation states. Both CID and ETD reveal chemistry that reflects the condensed-phase redox behavior of the 4f and 5f elements." @default.
• W2312837375 created "2016-06-24" @default.
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• W2312837375 date "2014-11-05" @default.
• W2312837375 modified "2023-09-25" @default.
• W2312837375 title "Dissociation of Diglycolamide Complexes of Ln³⁺ (Ln = La–Lu) and An³⁺ (An = Pu, Am, Cm): Redox Chemistry of 4f and 5f Elements in the Gas Phase Parallels Solution Behavior" @default.
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• W2312837375 doi "https://doi.org/10.1021/ic501985p" @default.
• W2312837375 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25372998" @default.
• W2312837375 hasPublicationYear "2014" @default.
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