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• W2312839097 abstract "(R)-1-Arylethanols and other secondary alcohols were prepared at high ee (>90%) by oxidative kinetic resolution using resting cells of the yeast Candida albicans CCT 0776. The deracemization process of 1-phenylethanol 1a catalyzed by the yeast was elucidated by studying each step separately. It was determined that the reaction occurred via cyclic deracemization, to give (R)-1a in 89% yield and with 98% ee. Finally, deracemization by stereoinversion of rac-1a was studied using a tandem process of C. albicans followed by Lactobacillus brevis CCT 3745. Inverting the sequence of these microorganisms produced an enantiomerically pure antipode." @default.
• W2312839097 created "2016-06-24" @default.
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• W2312839097 date "2016-06-01" @default.
• W2312839097 modified "2023-10-03" @default.
• W2312839097 title "Deracemization of 1-phenylethanol via tandem biocatalytic oxidation and reduction" @default.
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• W2312839097 doi "https://doi.org/10.1016/j.tetasy.2016.03.008" @default.
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