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- W2312857579 abstract "The hydrogen isotope effects are systematically investigated by measuring the equilibrium separation factor (α) in Ti–V–Cr alloys with mixed H–D systems at 30 °C. We find that all of the alloys are BCC structures except for TiCr. Interestingly, α displays a parabolic relation with respect to the number of valence electrons per metal atom (e/a) for V 40 at %. Moreover, significant inverse isotope effects appear at e/a = 4.6–5.2 (α > 1.3), and α reaches its maximum value at e/a = 5.0 (α = 1.47). The lattice constants dependent on α are studied by adjusting the vanadium content at e/a = 5.0, revealing a linear decrease of α as a function of the lattice constants. All the results indicate that the hydrogen isotope effects can be detected in Ti–V–Cr alloys with e/a and lattice constants." @default.
- W2312857579 created "2016-06-24" @default.
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- W2312857579 date "2015-02-09" @default.
- W2312857579 modified "2023-10-18" @default.
- W2312857579 title "Hydrogen Isotope Effects in Ti–V–Cr Alloy Hydrides" @default.
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- W2312857579 doi "https://doi.org/10.1021/jp5113685" @default.
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