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• W2312883658 endingPage "7394" @default.
• W2312883658 startingPage "7383" @default.
• W2312883658 abstract "It is known that electron donating groups have quite a different effect on the π-delocalization of a conjugate system when bonded at ortho and para as compared to meta positions in the phenyl ring. In the present work, the BF2 complex of 1-phenyl-3-(3,5-dimethoxyphenyl)-propane-1,3-dione (1), a molecule with two methoxy groups in one of the phenyl rings at meta positions, was prepared. Compound 1 exists as two polymorphs having different mutual orientations of the two methoxy groups: in polymorph A away from each other (termed anti), while in polymorph B one methoxy group is oriented toward the other (syn–anti). In both crystals, the molecules which are antiparallel (the subPh rings as well as dioxaborine are on opposite sides) form stacks through face-to-face π–π interactions, while in polymorph A the crystal packing is further stabilized by intermolecular C(phenyl)–H···F and C(methoxy)–H···F hydrogen bonds. Solid A possesses numerous chromic effects, including mechano-, thermo-, and chronochromism, though the latter to a lesser extent, as well as the effect of rearrangement of the amorphous phase into a more stable crystalline phase A, associated with crystallization-induced emission enhancement (CIEE). The solid-state emission can be repeatedly switched regarding its color and efficiency with excellent reversibility by external stimuli. On the other hand, crystalline solid B undergoes thermal interconversion of syn–anti to the anti conformer. Compound 1 shows a solvatochromic effect (SE), is aggregation-induced emission (AIE) active, and through the sublimation process displays self-assembling crystalline platelike microstructures or microfibers that reveal an obvious optical waveguide effect." @default.
• W2312883658 created "2016-06-24" @default.
• W2312883658 creator A5004729361 @default.
• W2312883658 creator A5010282602 @default.
• W2312883658 creator A5013442122 @default.
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• W2312883658 date "2014-05-12" @default.
• W2312883658 modified "2023-10-18" @default.
• W2312883658 title "Crystal Structures and Emission Properties of the BF₂ Complex 1-Phenyl-3-(3,5-dimethoxyphenyl)-propane-1,3-dione: Multiple Chromisms, Aggregation- or Crystallization-Induced Emission, and the Self-Assembly Effect" @default.
• W2312883658 cites W1929445715 @default.
• W2312883658 cites W1963505485 @default.
• W2312883658 cites W1964603841 @default.
• W2312883658 cites W1965493566 @default.
• W2312883658 cites W1973856006 @default.
• W2312883658 cites W1974746822 @default.
• W2312883658 cites W1977396648 @default.
• W2312883658 cites W1981754932 @default.
• W2312883658 cites W1983705293 @default.
• W2312883658 cites W1984990803 @default.
• W2312883658 cites W1986996260 @default.
• W2312883658 cites W1993058251 @default.
• W2312883658 cites W1993943878 @default.
• W2312883658 cites W2001689795 @default.
• W2312883658 cites W2007278339 @default.
• W2312883658 cites W2011817526 @default.
• W2312883658 cites W2020834630 @default.
• W2312883658 cites W2021779462 @default.
• W2312883658 cites W2026050524 @default.
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• W2312883658 cites W2032116061 @default.
• W2312883658 cites W2032185182 @default.
• W2312883658 cites W2034822115 @default.
• W2312883658 cites W2035848294 @default.
• W2312883658 cites W2041340670 @default.
• W2312883658 cites W2041702532 @default.
• W2312883658 cites W2045176933 @default.
• W2312883658 cites W2047039418 @default.
• W2312883658 cites W2052704540 @default.
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• W2312883658 cites W2060800190 @default.
• W2312883658 cites W2063060519 @default.
• W2312883658 cites W2063411559 @default.
• W2312883658 cites W2068905091 @default.
• W2312883658 cites W2077188122 @default.
• W2312883658 cites W2078171474 @default.
• W2312883658 cites W2080553196 @default.
• W2312883658 cites W2081198268 @default.
• W2312883658 cites W2081335506 @default.
• W2312883658 cites W2082984209 @default.
• W2312883658 cites W2083827540 @default.
• W2312883658 cites W2084534953 @default.
• W2312883658 cites W2089158509 @default.
• W2312883658 cites W2089317723 @default.
• W2312883658 cites W2090385061 @default.
• W2312883658 cites W2094989517 @default.
• W2312883658 cites W2098157174 @default.
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• W2312883658 cites W2122746064 @default.
• W2312883658 cites W2125058755 @default.
• W2312883658 cites W2131642901 @default.
• W2312883658 cites W2145423767 @default.
• W2312883658 cites W2154023845 @default.
• W2312883658 cites W2158274572 @default.
• W2312883658 cites W2159182565 @default.
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• W2312883658 doi "https://doi.org/10.1021/ja501977a" @default.
• W2312883658 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24819115" @default.
• W2312883658 hasPublicationYear "2014" @default.
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