FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2312901248> ?p ?o ?g. }

• W2312901248 endingPage "13095" @default.
• W2312901248 startingPage "13089" @default.
• W2312901248 abstract "A relationship between the size of metal particles and their catalytic activity has been established over a nanometer scale (2–10 nm). However, application on a subnanometer scale (0.5–2 nm) is difficult, a possible reason being that the activity no longer relies on the size but rather the geometric structure as a cluster (or superatomic) compound. We now report that the catalytic activity for the oxygen reduction reaction (ORR) significantly increased when only one atom was removed from a magic number cluster composed of 13-platinum atoms (Pt13). The synthesis with an atomic-level precision was successfully achieved by using a dendrimer ligand as the macromolecular template strictly defining the number of metal atoms. It was quite surprising that the Pt12 cluster exhibited more than 2-fold catalytic activity compared with that of the Pt13 cluster. ESI-TOF-mass and EXAFS analyses provided information about the structures. These analyses suggested that the Pt12 has a deformed coordination, while the Pt13 has a well-known icosahedral atomic coordination as part of the stable cluster series. Theoretical analyses based on density functional theory (DFT) also supported this idea. The present results suggest potential activity of the metastable clusters although they have been “missing” species in conventional statistical synthesis." @default.
• W2312901248 created "2016-06-24" @default.
• W2312901248 creator A5031793037 @default.
• W2312901248 creator A5036341706 @default.
• W2312901248 creator A5040284881 @default.
• W2312901248 creator A5048569737 @default.
• W2312901248 creator A5057001892 @default.
• W2312901248 creator A5062880722 @default.
• W2312901248 date "2013-08-19" @default.
• W2312901248 modified "2023-10-01" @default.
• W2312901248 title "Magic Number Pt₁₃ and Misshapen Pt₁₂ Clusters: Which One is the Better Catalyst?" @default.
• W2312901248 cites W1964148670 @default.
• W2312901248 cites W1970439390 @default.
• W2312901248 cites W1973593874 @default.
• W2312901248 cites W1983735836 @default.
• W2312901248 cites W1988792232 @default.
• W2312901248 cites W1990348970 @default.
• W2312901248 cites W1991079244 @default.
• W2312901248 cites W1993012609 @default.
• W2312901248 cites W1996419546 @default.
• W2312901248 cites W1997216543 @default.
• W2312901248 cites W2001231467 @default.
• W2312901248 cites W2002922257 @default.
• W2312901248 cites W2006170424 @default.
• W2312901248 cites W2008162921 @default.
• W2312901248 cites W2013288190 @default.
• W2312901248 cites W2014452628 @default.
• W2312901248 cites W2019102652 @default.
• W2312901248 cites W2022299938 @default.
• W2312901248 cites W2022956627 @default.
• W2312901248 cites W2024285405 @default.
• W2312901248 cites W2024451528 @default.
• W2312901248 cites W2032362534 @default.
• W2312901248 cites W2039486509 @default.
• W2312901248 cites W2051260837 @default.
• W2312901248 cites W2051393012 @default.
• W2312901248 cites W2055747486 @default.
• W2312901248 cites W2057893874 @default.
• W2312901248 cites W2058426254 @default.
• W2312901248 cites W2058704492 @default.
• W2312901248 cites W2061820211 @default.
• W2312901248 cites W2065414271 @default.
• W2312901248 cites W2067009832 @default.
• W2312901248 cites W2067777626 @default.
• W2312901248 cites W2071434438 @default.
• W2312901248 cites W2072235832 @default.
• W2312901248 cites W2077490493 @default.
• W2312901248 cites W2077581728 @default.
• W2312901248 cites W2084874576 @default.
• W2312901248 cites W2087630751 @default.
• W2312901248 cites W2088357042 @default.
• W2312901248 cites W2095146078 @default.
• W2312901248 cites W2102515376 @default.
• W2312901248 cites W2107517269 @default.
• W2312901248 cites W2108415968 @default.
• W2312901248 cites W2115729799 @default.
• W2312901248 cites W2115967600 @default.
• W2312901248 cites W2126954122 @default.
• W2312901248 cites W2127205378 @default.
• W2312901248 cites W2133616865 @default.
• W2312901248 cites W2139406518 @default.
• W2312901248 cites W2142011560 @default.
• W2312901248 cites W2158546379 @default.
• W2312901248 cites W2160248419 @default.
• W2312901248 cites W2171093931 @default.
• W2312901248 cites W2171385314 @default.
• W2312901248 cites W2318005455 @default.
• W2312901248 cites W2321866205 @default.
• W2312901248 cites W3004618007 @default.
• W2312901248 doi "https://doi.org/10.1021/ja405922m" @default.
• W2312901248 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23902457" @default.
• W2312901248 hasPublicationYear "2013" @default.
• W2312901248 type Work @default.
• W2312901248 sameAs 2312901248 @default.
• W2312901248 citedByCount "169" @default.
• W2312901248 countsByYear W23129012482013 @default.
• W2312901248 countsByYear W23129012482014 @default.
• W2312901248 countsByYear W23129012482015 @default.
• W2312901248 countsByYear W23129012482016 @default.
• W2312901248 countsByYear W23129012482017 @default.
• W2312901248 countsByYear W23129012482018 @default.
• W2312901248 countsByYear W23129012482019 @default.
• W2312901248 countsByYear W23129012482020 @default.
• W2312901248 countsByYear W23129012482021 @default.
• W2312901248 countsByYear W23129012482022 @default.
• W2312901248 countsByYear W23129012482023 @default.
• W2312901248 crossrefType "journal-article" @default.
• W2312901248 hasAuthorship W2312901248A5031793037 @default.
• W2312901248 hasAuthorship W2312901248A5036341706 @default.
• W2312901248 hasAuthorship W2312901248A5040284881 @default.
• W2312901248 hasAuthorship W2312901248A5048569737 @default.
• W2312901248 hasAuthorship W2312901248A5057001892 @default.
• W2312901248 hasAuthorship W2312901248A5062880722 @default.
• W2312901248 hasConcept C107861141 @default.
• W2312901248 hasConcept C113709186 @default.
• W2312901248 hasConcept C116569031 @default.
• W2312901248 hasConcept C119824511 @default.
• W2312901248 hasConcept C121332964 @default.

• next