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- W2312904826 abstract "Three new Ln(III) complexes based on 2,2'-bipyridine [Ln(hfac)3(bpy)] (Ln = Dy (1), Tb (2), or Ho (3); hfac = hexafluoroacetylacetonate; and bpy = 2,2'-bipyridine) have been synthesized and characterized structurally and magnetically. Single-crystal X-ray analysis shows that all these complexes contain one [Ln(hfac)3(bpy)] unit in which a center Ln(III) ion is surrounded with a slightly distorted square-antiprismatic LnO6N2 coordination sphere formed by three bischelate hfac anions and one bpy ligand. Both static and dynamic magnetic properties were studied for complex 1, which is proved to be a new single-ion magnet. The luminescence characterizations of complexes 1 and 2 are also studied in this paper." @default.
- W2312904826 created "2016-06-24" @default.
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- W2312904826 date "2013-06-07" @default.
- W2312904826 modified "2023-09-25" @default.
- W2312904826 title "Syntheses, Structures, and Magnetic and Luminescence Properties of a New Dy<sup>III</sup>-Based Single-Ion Magnet" @default.
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- W2312904826 doi "https://doi.org/10.1021/ic400006n" @default.
- W2312904826 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23746218" @default.
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