Matches in SemOpenAlex for { <https://semopenalex.org/work/W2313065704> ?p ?o ?g. }
Showing items 1 to 97 of
97
with 100 items per page.
- W2313065704 endingPage "207" @default.
- W2313065704 startingPage "193" @default.
- W2313065704 abstract "Abstract Some of the problems encountered in the determination of the electronic spectra of μ-peroxodicobalt(III) complexes are discussed. After account is taken of the common formation of mixtures of different μ-peroxocomplexes upon oxygenation of Co(II)-ligand solutions, it can be concluded that three classes of spectra exist. Planar single-bridged complexes exhibit a strong (∊ ≃ 12,500) π∗h→dσ-∗ peroxide LMCT band at 300–310 nm, with a weak (∊ ≃ 600) π∗v →d∊∗ band at 425–430 nm. Nonplanar (dihedral angle near 145°) single-bridged complexes exhibit two strong (∊ ≃ 6000) π∗(02- 2) → dσ∗ bands near 320 and 390 nm. Dibridged μ.-(OH-,02- 2) complexes, with a dihedral angle near 60°, exhibit one broad peroxide LMCT band at ≃ 355 nm (∊ ≃ 6000). The latter compounds have an additional band near 280 nm which is not due to peroxide. All of the peroxide LMCT spectra are shown to be consistent with a simple model that assumes a sinusoidal dependence of π∗(02 2) energies and σ-overlaps upon the dihedral angle." @default.
- W2313065704 created "2016-06-24" @default.
- W2313065704 creator A5004361433 @default.
- W2313065704 date "1987-12-01" @default.
- W2313065704 modified "2023-09-25" @default.
- W2313065704 title "The Electronic Spectra of μ-Peroxodicobalt(III) Complexes" @default.
- W2313065704 cites W1580934584 @default.
- W2313065704 cites W1946759439 @default.
- W2313065704 cites W1964886565 @default.
- W2313065704 cites W1966618276 @default.
- W2313065704 cites W1967544609 @default.
- W2313065704 cites W1980968165 @default.
- W2313065704 cites W1985232551 @default.
- W2313065704 cites W1985753481 @default.
- W2313065704 cites W1987010776 @default.
- W2313065704 cites W1990759253 @default.
- W2313065704 cites W1997918469 @default.
- W2313065704 cites W1998276844 @default.
- W2313065704 cites W2004180108 @default.
- W2313065704 cites W2010791251 @default.
- W2313065704 cites W2011172837 @default.
- W2313065704 cites W2012783623 @default.
- W2313065704 cites W2020512290 @default.
- W2313065704 cites W2025879238 @default.
- W2313065704 cites W2055898964 @default.
- W2313065704 cites W2065441276 @default.
- W2313065704 cites W2065658669 @default.
- W2313065704 cites W2073787948 @default.
- W2313065704 cites W2080604673 @default.
- W2313065704 cites W2088774147 @default.
- W2313065704 cites W2092201064 @default.
- W2313065704 cites W2094413922 @default.
- W2313065704 cites W2094927944 @default.
- W2313065704 cites W2101515329 @default.
- W2313065704 cites W2159196667 @default.
- W2313065704 cites W2312720366 @default.
- W2313065704 cites W2330976639 @default.
- W2313065704 cites W2952707844 @default.
- W2313065704 cites W3136146431 @default.
- W2313065704 cites W4233782699 @default.
- W2313065704 doi "https://doi.org/10.1080/02603598708072290" @default.
- W2313065704 hasPublicationYear "1987" @default.
- W2313065704 type Work @default.
- W2313065704 sameAs 2313065704 @default.
- W2313065704 citedByCount "8" @default.
- W2313065704 countsByYear W23130657042012 @default.
- W2313065704 crossrefType "journal-article" @default.
- W2313065704 hasAuthorship W2313065704A5004361433 @default.
- W2313065704 hasConcept C112887158 @default.
- W2313065704 hasConcept C121332964 @default.
- W2313065704 hasConcept C121684516 @default.
- W2313065704 hasConcept C1276947 @default.
- W2313065704 hasConcept C134786449 @default.
- W2313065704 hasConcept C178790620 @default.
- W2313065704 hasConcept C185592680 @default.
- W2313065704 hasConcept C2781048764 @default.
- W2313065704 hasConcept C32909587 @default.
- W2313065704 hasConcept C41008148 @default.
- W2313065704 hasConcept C41999313 @default.
- W2313065704 hasConcept C4839761 @default.
- W2313065704 hasConcept C8010536 @default.
- W2313065704 hasConcept C89025888 @default.
- W2313065704 hasConceptScore W2313065704C112887158 @default.
- W2313065704 hasConceptScore W2313065704C121332964 @default.
- W2313065704 hasConceptScore W2313065704C121684516 @default.
- W2313065704 hasConceptScore W2313065704C1276947 @default.
- W2313065704 hasConceptScore W2313065704C134786449 @default.
- W2313065704 hasConceptScore W2313065704C178790620 @default.
- W2313065704 hasConceptScore W2313065704C185592680 @default.
- W2313065704 hasConceptScore W2313065704C2781048764 @default.
- W2313065704 hasConceptScore W2313065704C32909587 @default.
- W2313065704 hasConceptScore W2313065704C41008148 @default.
- W2313065704 hasConceptScore W2313065704C41999313 @default.
- W2313065704 hasConceptScore W2313065704C4839761 @default.
- W2313065704 hasConceptScore W2313065704C8010536 @default.
- W2313065704 hasConceptScore W2313065704C89025888 @default.
- W2313065704 hasIssue "4" @default.
- W2313065704 hasLocation W23130657041 @default.
- W2313065704 hasOpenAccess W2313065704 @default.
- W2313065704 hasPrimaryLocation W23130657041 @default.
- W2313065704 hasRelatedWork W1577007446 @default.
- W2313065704 hasRelatedWork W1976604357 @default.
- W2313065704 hasRelatedWork W1993052885 @default.
- W2313065704 hasRelatedWork W2064549172 @default.
- W2313065704 hasRelatedWork W2081701154 @default.
- W2313065704 hasRelatedWork W2090399876 @default.
- W2313065704 hasRelatedWork W2114042543 @default.
- W2313065704 hasRelatedWork W2346897461 @default.
- W2313065704 hasRelatedWork W2620865887 @default.
- W2313065704 hasRelatedWork W2950048728 @default.
- W2313065704 hasVolume "6" @default.
- W2313065704 isParatext "false" @default.
- W2313065704 isRetracted "false" @default.
- W2313065704 magId "2313065704" @default.
- W2313065704 workType "article" @default.