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• W2313191036 abstract "Cocrystallization of diiodine and carbon disulfide with the two common fullerenes, C60 and C70, has been examined. The binary cocrystal, C70·I2, readily formed when a solution of diiodine in diethyl ether was layered over C70 dissolved in toluene, chlorobenzene, or 1,2-dichlorobenzene, but no binary cocrystal of diiodine and C60 could be obtained despite persistent efforts. The ternary cocrystal, C70·0.85I2·0.15CS2, which was grown from a carbon disulfide solution of C70 and a benzene solution of diiodine, is isostructural with C70·I2 but has 15% of the diiodine sites replaced with carbon disulfide. In contrast, C70·0.68I2·0.32CS2, which was obtained from diffusion of a cyclohexane solution of diiodine into a carbon disulfide solution of C70, is a unique ternary cocrystal that is not related to any binary cocrystal of C70 with diiodine or carbon disulfide. Crystals of 2C60·2.46CS2·0.54I2 were obtained from a saturated carbon disulfide solution of diiodine and C60. Black crystals of 2C60·2.46CS2·0.54I2 form in a different space group from those of the solvate 2C60·3CS2 but have a very similar structure. Remarkably, diiodine molecules fractionally replace carbon disulfide in only two of the three independent sites within this crystal." @default.
• W2313191036 created "2016-06-24" @default.
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• W2313191036 date "2014-09-02" @default.
• W2313191036 modified "2023-09-26" @default.
• W2313191036 title "Incorporation of the Similarly Sized Molecules, Diiodine and Carbon Disulfide, into Cocrystals Formed with the Fullerenes, C₆₀ or C₇₀" @default.
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• W2313191036 doi "https://doi.org/10.1021/cg500817w" @default.
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