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- W2313203733 abstract "The structural and magnetic properties of a new series of iridium-based honeycomb lattices with the formula Na3−δ(Na1−xMgx)Ir2O6 (0≤x≤1) are reported. As x and δ are increased, the honeycomb lattice contracts and the strength of the antiferromagnetic interactions decreases systematically due to a reduction in Ir–O–Ir bond angles. Samples with imperfect stoichiometry exhibit disordered magnetic freezing at temperatures Tf between 3.4 K and 5 K. This glassy magnetism likely arises due to the presence of non-magnetic Ir3+, which are distributed randomly throughout the lattice, with a possible additional contribution from stacking faults. Together, these results demonstrate that chemical defects and non-stoichiometry have a significant effect on the magnetism of compounds in the A2IrO3 materials family." @default.
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- W2313203733 date "2015-04-01" @default.
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- W2313203733 title "Evolution of magnetism in the<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML altimg=si0033.gif overflow=scroll><mml:msub><mml:mrow><mml:mi>Na</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn><mml:mo>−</mml:mo><mml:mi>δ</mml:mi></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:msub><mml:mrow><mml:mi>Na</mml:mi></mml:mrow><mml:mrow><mml:mn>1</mml:mn><mml:mo>−</mml:mo><mml:mi>x</mml:mi></mml:mrow></mml:msub><mml:msub><mml:mrow><mml:mi>Mg</mml:mi></mml:mrow><mml:mrow><mml:mi>x</mml:mi></mml:…" @default.
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- W2313203733 doi "https://doi.org/10.1016/j.jssc.2014.03.013" @default.
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