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- W2313263295 abstract "Low temperature, infrared absorption spectra of gadolinium gallium garnet crystals doped with Ce are presented. In the region of intraconfigurational 4$f$-4$f$ transitions the spectra exhibit existence of at least two different, major Ce${}^{3+}$ related centers in the GGG crystals and also some other centers at lower concentration. The spectrum of 4$f$-4$f$ intrashell transitions of Ce${}^{3+}$ ions extends up to about 3700 cm${}^{ensuremath{-}1}$ due to the large splitting of the ${}^{2}$${F}_{7/2}$ excited state. In the visible region the absorption spectrum shows influence of symmetry-related selection rules. The absorption coefficient changes in the region of 4${f}^{1}$-5${d}^{1}$ transitions due to thermal population of the second level, belonging to the ${}^{2}$${F}_{5/2}$ ground state. This suggests that the symmetry of the site occupied by Ce${}^{3+}$ ions, which substitute Gd${}^{3+}$, is higher than ${D}_{2}$ expected for garnet hosts." @default.
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- W2313263295 date "2013-01-16" @default.
- W2313263295 modified "2023-10-18" @default.
- W2313263295 title "Evidence of multicenter structure of cerium ions in gadolinium gallium garnet crystals studied by infrared absorption spectroscopy" @default.
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- W2313263295 doi "https://doi.org/10.1103/physrevb.87.045114" @default.
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