Matches in SemOpenAlex for { <https://semopenalex.org/work/W2313302577> ?p ?o ?g. }
- W2313302577 endingPage "5635" @default.
- W2313302577 startingPage "5625" @default.
- W2313302577 abstract "The title compound [PtMe2(bpe)], 1, bpe = 1,2-bis(2-pyridyl)ethane, is easily oxidized to give octahedral organoplatinum(IV) complexes, and the subsequent chemistry is profoundly influenced by the accompanying strain induced in the seven-membered Pt(bpe) chelate ring. In reactions with bromine or iodine, X2, the platinum(IV) complexes [PtX2Me2(bpe)] are formed initially, but they decompose primarily by reductive elimination of MeX to give ultimately the platinum(II) complexes [PtX2(bpe)]. When X = I, a minor reaction occurred to give the first example of metalation of a CH2 group of the bpe ligand. On reaction of 1 with HCl, the initial product [PtHClMe2(bpe)] undergoes reductive elimination of methane to form [PtClMe(bpe)]. In contrast, methyl iodide reacts with 1 to give [PtIMe3(bpe)], and this decomposes by loss of the bpe ligand to give the cubane [(PtIMe3)4] and not by reductive elimination. Finally, a new class of platinum(IV) double cubane clusters was obtained on oxidation of complex 1 either with hydrogen peroxide to give [Pt4(μ-OH)4(μ3-OH)2Me10], as a mixed complex with [PtMe2(CO3)(bpe)], or with oxygen in methanol to give [Pt4(μ-OH)2(μ-OMe)2(μ3-OMe)2Me10]." @default.
- W2313302577 created "2016-06-24" @default.
- W2313302577 creator A5002714721 @default.
- W2313302577 creator A5012804768 @default.
- W2313302577 creator A5021402070 @default.
- W2313302577 date "2011-07-18" @default.
- W2313302577 modified "2023-09-26" @default.
- W2313302577 title "The Chemistry of [PtMe2(1,2-bis(2-pyridyl)ethane)]: Remarkable Impact of an Easily Dissociated Chelate Ligand" @default.
- W2313302577 cites W1900623949 @default.
- W2313302577 cites W1930587484 @default.
- W2313302577 cites W1964005222 @default.
- W2313302577 cites W1967600412 @default.
- W2313302577 cites W1967835159 @default.
- W2313302577 cites W1968698976 @default.
- W2313302577 cites W1969928586 @default.
- W2313302577 cites W1972497605 @default.
- W2313302577 cites W1974893883 @default.
- W2313302577 cites W1981520146 @default.
- W2313302577 cites W1981909269 @default.
- W2313302577 cites W1983110631 @default.
- W2313302577 cites W1984206834 @default.
- W2313302577 cites W1986851325 @default.
- W2313302577 cites W1987828043 @default.
- W2313302577 cites W1988594523 @default.
- W2313302577 cites W1990514145 @default.
- W2313302577 cites W1990514192 @default.
- W2313302577 cites W1990888602 @default.
- W2313302577 cites W1990960072 @default.
- W2313302577 cites W1992087078 @default.
- W2313302577 cites W1996504075 @default.
- W2313302577 cites W1999322773 @default.
- W2313302577 cites W2000714689 @default.
- W2313302577 cites W2002620301 @default.
- W2313302577 cites W2004425426 @default.
- W2313302577 cites W2005661768 @default.
- W2313302577 cites W2006232300 @default.
- W2313302577 cites W2007232572 @default.
- W2313302577 cites W2007970047 @default.
- W2313302577 cites W2008817319 @default.
- W2313302577 cites W2010639764 @default.
- W2313302577 cites W2012320121 @default.
- W2313302577 cites W2013672217 @default.
- W2313302577 cites W2015554875 @default.
- W2313302577 cites W2017658721 @default.
- W2313302577 cites W2020222056 @default.
- W2313302577 cites W2023120481 @default.
- W2313302577 cites W2028984595 @default.
- W2313302577 cites W2034153212 @default.
- W2313302577 cites W2034181168 @default.
- W2313302577 cites W2040299058 @default.
- W2313302577 cites W2047171111 @default.
- W2313302577 cites W2047289623 @default.
- W2313302577 cites W2048135228 @default.
- W2313302577 cites W2048502793 @default.
- W2313302577 cites W2049938993 @default.
- W2313302577 cites W2050023115 @default.
- W2313302577 cites W2052610481 @default.
- W2313302577 cites W2056526583 @default.
- W2313302577 cites W2059420426 @default.
- W2313302577 cites W2060731593 @default.
- W2313302577 cites W2062477343 @default.
- W2313302577 cites W2062771029 @default.
- W2313302577 cites W2063871496 @default.
- W2313302577 cites W2066671943 @default.
- W2313302577 cites W2069503178 @default.
- W2313302577 cites W2070300925 @default.
- W2313302577 cites W2071733447 @default.
- W2313302577 cites W2071794970 @default.
- W2313302577 cites W2074602525 @default.
- W2313302577 cites W2075097387 @default.
- W2313302577 cites W2075999741 @default.
- W2313302577 cites W2079757818 @default.
- W2313302577 cites W2083160150 @default.
- W2313302577 cites W2084854951 @default.
- W2313302577 cites W2085359187 @default.
- W2313302577 cites W2086527012 @default.
- W2313302577 cites W2086957099 @default.
- W2313302577 cites W2087261436 @default.
- W2313302577 cites W2092315973 @default.
- W2313302577 cites W2093457083 @default.
- W2313302577 cites W2095153943 @default.
- W2313302577 cites W2095539061 @default.
- W2313302577 cites W2101584728 @default.
- W2313302577 cites W2111157839 @default.
- W2313302577 cites W2113440143 @default.
- W2313302577 cites W2131747050 @default.
- W2313302577 cites W2148185325 @default.
- W2313302577 cites W2150345533 @default.
- W2313302577 cites W2319930853 @default.
- W2313302577 cites W2333100149 @default.
- W2313302577 cites W2333746167 @default.
- W2313302577 cites W2334786538 @default.
- W2313302577 cites W2949149995 @default.
- W2313302577 cites W2950486872 @default.
- W2313302577 cites W2951020462 @default.
- W2313302577 cites W3137898069 @default.
- W2313302577 cites W3897814 @default.
- W2313302577 cites W2057767059 @default.