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• W2313303786 abstract "The orientation of cylinder-forming poly(styrene-block-methyl methacrylate) [P(S-b-MMA)] was investigated on two sets of polymeric surface treatments: 10 para-substituted polystyrene derivatives with <10 mol % poly(4-vinylbenzyl azide) and a series of poly(styrene-random-4-vinylbenzyl azide) [P(S-r-VBzAz)] copolymers with 5-100 mol % poly(4-vinylbenzyl azide). The copolymers were spin-coated to form thin films and then cross-linked by heating. The resulting films exhibited a range of surface tensions from 21 to 45 dyn/cm. Perpendicular orientation of P(S-b-MMA) cylinders was achieved with poly(p-bromostyrene) and all the [P(S-r-VBzAz)] copolymer surface treatments, most notably the homopolymer of poly(4-vinylbenzyl azide). Films made from these simple copolymers are as effective as random terpolymer alignment layers commonly made from both block monomers and a cross-linkable monomer." @default.
• W2313303786 created "2016-06-24" @default.
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• W2313303786 date "2011-01-07" @default.
• W2313303786 modified "2023-09-30" @default.
• W2313303786 title "Polymeric Cross-Linked Surface Treatments for Controlling Block Copolymer Orientation in Thin Films" @default.
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• W2313303786 doi "https://doi.org/10.1021/la1042958" @default.
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