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- W2313308844 abstract "A series of 2,3,4,5-tetraphenylboroles substituted with different aromatic heterocycles (thiophene, furan, pyrrole, and dithiophene) in the 1-position were synthesized and characterized by means of NMR, elemental analysis, and X-ray crystallography. In contrast to known 2,3,4,5-tetraphenylboroles, X-ray diffraction revealed a nearly coplanar arrangement of the aromatic heterocycles and the antiaromatic borole scaffold as a result of π-conjugation, which could be substantiated by DFT calculations. Furthermore, the 2,2'-dithiophene-bridged bisborole (14) exhibits a large bathochromic shift in the absorption spectrum, demonstrating the exceptional Lewis acidity of the nonannulated borolyl moiety." @default.
- W2313308844 created "2016-06-24" @default.
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- W2313308844 date "2012-12-04" @default.
- W2313308844 modified "2023-09-26" @default.
- W2313308844 title "1-Heteroaromatic-Substituted Tetraphenylboroles: π–π Interactions Between Aromatic and Antiaromatic Rings Through a B–C Bond" @default.
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- W2313308844 doi "https://doi.org/10.1021/ja309935t" @default.
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- W2313308844 hasPublicationYear "2012" @default.
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