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- W2313334524 abstract "Stable 1-bromo-1-silacyclopropanes were synthesized in high yields from the reaction of the stable bromotrisylsilylenoid 1 (trisyl = C(SiMe3)3) with olefins such as styrene, trimethylvinylsilane, triethylvinylsilane, and dimethylphenylvinylsilane, a new synthetic route for silacyclopropanes. The structure of bromosilacyclopropane 5 was confirmed by X-ray analysis. In the presence of excess MeOH the phenyl-substituted bromosilacyclopropane 2 underwent regioselective ring opening to give the corresponding product 6. In contrast, the reaction of silyl-substituted bromosilacyclopropane 5 with MeOH gave only the product of nucleophilic substitution at the silicon atom, 1-methoxy-1-silacyclopropane 7, without any ring opening. Furthermore, the bromosilacyclopropane 2 extruded bromosilylene 8 through a thermal cycloreversion reaction." @default.
- W2313334524 created "2016-06-24" @default.
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- W2313334524 date "2012-07-17" @default.
- W2313334524 modified "2023-10-10" @default.
- W2313334524 title "A New Synthetic Route for Silacyclopropanes: Reactions of a Bromosilylenoid with Olefins" @default.
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- W2313334524 doi "https://doi.org/10.1021/om3005349" @default.
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