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• W2313372387 abstract "The constants of thermolysis rate of C6H5(CH2)nO(CH2)mC6H5 ethers were measured in conditions close to those of coal liquefaction (hydrogen pressure of 8.5 MPa; temperature up to 410 °C) but minimizing secondary conversions (i.e. in ten-fold excess of tetralin). The ethers form the following reactivity series depending on n and m values: at 350 °C[0,1] ⪢ [0,2] ⪢ [1,1] > [1,2] > [2,2] ⪢ [0,0], and at 410 °C [0,1] ⪢ [0,2] > [1,2] > [1,1] > [2,2] ⪢ [0,0]. The mechanism and pathways of ether conversions were defined based on the changing concentrations of the intermediate and final reaction products. In the case of benzyl phenyl and dibenzyl ethers the thermolysis was accompanied by intramolecular rearrangements." @default.
• W2313372387 created "2016-06-24" @default.
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• W2313372387 date "1988-05-01" @default.
• W2313372387 modified "2023-09-27" @default.
• W2313372387 title "Effect of the structure of coal-related model ethers on the rate and mechanism of their thermolysis" @default.
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• W2313372387 doi "https://doi.org/10.1016/0016-2361(88)90294-3" @default.
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