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• W2313447101 startingPage "9284" @default.
• W2313447101 abstract "The evolution of an enantioselective total synthesis of (+)-18-epi-latrunculol A, a congener of the marine-sponge-derived latrunculins A and B, is reported. Key steps include a late-stage Mitsunobu macrolactonization to construct the 16-membered macrolactone, a mild Carreira alkynylation to unite the northern and southern hemispheres, a diastereoselective, acid-mediated δ-hydroxy enone cyclization/equilibration sequence, and a functional-group-tolerant cross-metathesis to access the enone cyclization precursor." @default.
• W2313447101 created "2016-06-24" @default.
• W2313447101 creator A5025348297 @default.
• W2313447101 creator A5066527875 @default.
• W2313447101 date "2014-09-22" @default.
• W2313447101 modified "2023-10-09" @default.
• W2313447101 title "Total Synthesis of (+)-18-<i>epi</i>-Latrunculol A: Development of a Synthetic Route" @default.
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• W2313447101 doi "https://doi.org/10.1021/jo501733m" @default.
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