FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2313481574> ?p ?o ?g. }

• W2313481574 endingPage "1493" @default.
• W2313481574 startingPage "1480" @default.
• W2313481574 abstract "A method developed for the first time, to create a huge number of ionic liquid (IL)-in-oil microemulsions has been discussed in our earlier publication (Rao, V. G.; Ghosh, S.; Ghatak, C.; Mandal, S.; Brahmachari, U.; Sarkar, N. J. Phys. Chem. B2012, 116, 2850–2855). Here, we present facile methods to adjust the structural parameters of microemulsions using different ionic liquids (ILs) as additives (polar phase). We have characterized ILs/[C4mim][AOT]/benzene ternary system by performing a phase behavior study, dynamic light scattering (DLS) measurements, and 1H NMR measurements. The IL loading capacity of microemulsions (area of single phase region) (i) increases with increase in alkyl chain length of cation of ILs and follows the trend [C6mim][TF2N] > [C4mim][TF2N] > [C2mim][TF2N], (ii) increases with decrease in cation anion interaction strength of added ILs and follows the trend [C4mim][TF2N] > [C4mim][PF6] > [C4mim][BF4]. So depending on the IL used, the amount of IL within the core of microemulsions can be easily manipulated to directly affect the size of aggregates in microemulsions. The size increase with increasing R value (R value is defined as the molar ratio of RTILs to [C4mim][AOT]) was found to be maximum in the case of [C2mim][TF2N]/[C4mim][AOT]/benzene microemulsions and follows the trend [C2mim][TF2N] > [C4mim][TF2N] > [C6mim][TF2N]. However, the size increase was almost the same with increase in R value in the case of ILs with different anions. The most promising fact about IL-in-oil microemulsions is their high thermal stability compared to that of aqueous microemulsions, so we investigated the effect of temperature on size of aggregates in microemulsions at R = 1.0. It is evident from dynamic light scattering measurements that the aggregates in microemulsions remain monodisperse in nature with increasing temperature, and in all the cases, the size of aggregates in microemulsions decreases with increasing temperature. The effect of water addition on IL-in-oil (IL/O) microemulsions was also studied in detail. By far, this is the first report where the effect of water addition on microemulsions containing hydrophobic ILs is being reported and compared with microemulsions containing hydrophilic ILs. We observed that the added water has a prominent effect on the microstructure of the microemulsions. In all the cases, 1H NMR spectra provide more detailed information about intra/intermolecular interactions thus affording a clear picture of locations of (i) the RTILs in RTILs/[C4mim][AOT]/benzene microemulsions and (ii) the added water molecules in microemulsions." @default.
• W2313481574 created "2016-06-24" @default.
• W2313481574 creator A5014249671 @default.
• W2313481574 creator A5022400299 @default.
• W2313481574 creator A5042593602 @default.
• W2313481574 creator A5062699094 @default.
• W2313481574 creator A5080767780 @default.
• W2313481574 date "2013-01-25" @default.
• W2313481574 modified "2023-10-16" @default.
• W2313481574 title "Phase Boundaries, Structural Characteristics, and NMR Spectra of Ionic Liquid-in-Oil Microemulsions Containing Double Chain Surface Active Ionic Liquid: A Comparative Study" @default.
• W2313481574 cites W1965504515 @default.
• W2313481574 cites W1965565422 @default.
• W2313481574 cites W1966431673 @default.
• W2313481574 cites W1966814961 @default.
• W2313481574 cites W1972926276 @default.
• W2313481574 cites W1978172516 @default.
• W2313481574 cites W1978294473 @default.
• W2313481574 cites W1979392810 @default.
• W2313481574 cites W1981660036 @default.
• W2313481574 cites W1981677312 @default.
• W2313481574 cites W1982249127 @default.
• W2313481574 cites W1986783306 @default.
• W2313481574 cites W1988647691 @default.
• W2313481574 cites W1991483044 @default.
• W2313481574 cites W1991816360 @default.
• W2313481574 cites W1992087394 @default.
• W2313481574 cites W1993021267 @default.
• W2313481574 cites W1997120248 @default.
• W2313481574 cites W1998650991 @default.
• W2313481574 cites W1998786069 @default.
• W2313481574 cites W2003008323 @default.
• W2313481574 cites W2003710001 @default.
• W2313481574 cites W2007196590 @default.
• W2313481574 cites W2008356280 @default.
• W2313481574 cites W2009157614 @default.
• W2313481574 cites W2014464559 @default.
• W2313481574 cites W2018030636 @default.
• W2313481574 cites W2020613457 @default.
• W2313481574 cites W2022066961 @default.
• W2313481574 cites W2022367796 @default.
• W2313481574 cites W2030158981 @default.
• W2313481574 cites W2030400557 @default.
• W2313481574 cites W2033005235 @default.
• W2313481574 cites W2034774750 @default.
• W2313481574 cites W2035943359 @default.
• W2313481574 cites W2036614481 @default.
• W2313481574 cites W2039326248 @default.
• W2313481574 cites W2041889894 @default.
• W2313481574 cites W2042241490 @default.
• W2313481574 cites W2042588207 @default.
• W2313481574 cites W2047131856 @default.
• W2313481574 cites W2048169412 @default.
• W2313481574 cites W2049296846 @default.
• W2313481574 cites W2050503887 @default.
• W2313481574 cites W2050651797 @default.
• W2313481574 cites W2051656429 @default.
• W2313481574 cites W2059606975 @default.
• W2313481574 cites W2062082373 @default.
• W2313481574 cites W2074070265 @default.
• W2313481574 cites W2075772293 @default.
• W2313481574 cites W2076588983 @default.
• W2313481574 cites W2077231474 @default.
• W2313481574 cites W2083152597 @default.
• W2313481574 cites W2083764931 @default.
• W2313481574 cites W2084551563 @default.
• W2313481574 cites W2085777302 @default.
• W2313481574 cites W2089608829 @default.
• W2313481574 cites W2090794556 @default.
• W2313481574 cites W2092565027 @default.
• W2313481574 cites W2093233380 @default.
• W2313481574 cites W2094588807 @default.
• W2313481574 cites W2095139866 @default.
• W2313481574 cites W2095366386 @default.
• W2313481574 cites W2107177409 @default.
• W2313481574 cites W2108598887 @default.
• W2313481574 cites W2126711202 @default.
• W2313481574 cites W2129253800 @default.
• W2313481574 cites W2135900088 @default.
• W2313481574 cites W2145301075 @default.
• W2313481574 cites W2149828333 @default.
• W2313481574 cites W2153646798 @default.
• W2313481574 cites W2160909843 @default.
• W2313481574 cites W2166444800 @default.
• W2313481574 cites W2170659351 @default.
• W2313481574 cites W2316816642 @default.
• W2313481574 cites W2317326155 @default.
• W2313481574 cites W2323249559 @default.
• W2313481574 cites W2328264160 @default.
• W2313481574 cites W2329043937 @default.
• W2313481574 cites W2330704062 @default.
• W2313481574 cites W2331104235 @default.
• W2313481574 cites W2331919679 @default.
• W2313481574 cites W4244506205 @default.
• W2313481574 doi "https://doi.org/10.1021/jp310616p" @default.
• W2313481574 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23311718" @default.
• W2313481574 hasPublicationYear "2013" @default.
• W2313481574 type Work @default.
• W2313481574 sameAs 2313481574 @default.

• next