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• W2313502442 startingPage "9210" @default.
• W2313502442 abstract "The treatment of LiAlH4 with 2, 3, or 4 equiv of the 3,5-disubstituted pyrazoles Ph2pzH or iPr2pzH afforded [Li(THF)2][AlH2(Ph2pz)2] (97%), [Li(THF)][AlH(Ph2pz)3] (96%), [Li(THF)4][Al(Ph2pz)4] (95%), and [Li(THF)][AlH(iPr2pz)3] (89%). The treatment of ZnCl2 with [Li(THF)][AlH(Ph2pz)3] afforded Zn(AlH(Ph2Pz)3)H (70%). X-ray crystal structures of these complexes demonstrated κ2 or κ3 coordination of the aluminum-based ligands to the Li or Zn ions. The treatment of [Li(THF)][AlH(Ph2pz)3] with MgBr2 or CoCl2 in THF/Et2O solutions, by contrast, afforded the pyrazolate transfer products Mg2Br2(Ph2pz)2(THF)3·2THF (25%) and Co2Cl2(Ph2pz)2(THF)3·THF (23%) as colorless and blue crystalline solids, respectively. An analogous treatment of [Li(THF)][AlH(Ph2pz)3] with MCl2 (M = Mn, Fe, Ni, Cu) afforded metal powders and H2, illustrating hydride transfer from Al to M as a competing reaction path." @default.
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• W2313502442 date "2011-08-30" @default.
• W2313502442 modified "2023-09-24" @default.
• W2313502442 title "Poly(pyrazolyl)aluminate Complexes Containing Aluminum–Hydrogen Bonds" @default.
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• W2313502442 doi "https://doi.org/10.1021/ic201541c" @default.
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