Matches in SemOpenAlex for { <https://semopenalex.org/work/W2313642483> ?p ?o ?g. }
- W2313642483 endingPage "601" @default.
- W2313642483 startingPage "593" @default.
- W2313642483 abstract "The formation of polycyclic aromatic hydrocarbons in combustion environments is linked to resonance stabilized free radicals. Here, we investigated the reaction dynamics of ground state carbon atoms, C((3)P(j)), with vinylacetylene at two collision energies of 18.8 kJ mol(-1) and 26.4 kJ mol(-1) employing the crossed molecular beam technique leading to two resonantly stabilized free radicals. The reaction was found to be governed by indirect scattering dynamics and to proceed without an entrance barrier through a long-lived collision complex to reach the products, n- and i-C(5)H(3) isomers via tight exit transition states. The reaction pathway taken is dependent on whether the carbon atom attacks the π electron density of the double or triple bond, both routes have been compared to the reactions of atomic carbon with ethylene and acetylene. Electronic structure/statistical theory calculations determined the product branching ratio to be 2:3 between the n- and i-C(5)H(3) isomers." @default.
- W2313642483 created "2016-06-24" @default.
- W2313642483 creator A5018375399 @default.
- W2313642483 creator A5038837508 @default.
- W2313642483 creator A5063132694 @default.
- W2313642483 creator A5080022083 @default.
- W2313642483 creator A5085005476 @default.
- W2313642483 date "2010-12-31" @default.
- W2313642483 modified "2023-10-01" @default.
- W2313642483 title "On the Formation of Resonantly Stabilized C<sub>5</sub>H<sub>3</sub> Radicals—A Crossed Beam and Ab Initio Study of the Reaction of Ground State Carbon Atoms with Vinylacetylene" @default.
- W2313642483 cites W1582990877 @default.
- W2313642483 cites W1631266563 @default.
- W2313642483 cites W1660605307 @default.
- W2313642483 cites W1874714014 @default.
- W2313642483 cites W1965428125 @default.
- W2313642483 cites W1965920978 @default.
- W2313642483 cites W1968736794 @default.
- W2313642483 cites W1971801881 @default.
- W2313642483 cites W1976056213 @default.
- W2313642483 cites W1979748898 @default.
- W2313642483 cites W1980877427 @default.
- W2313642483 cites W1982895703 @default.
- W2313642483 cites W1986055213 @default.
- W2313642483 cites W1986586613 @default.
- W2313642483 cites W1986864546 @default.
- W2313642483 cites W1989331599 @default.
- W2313642483 cites W1991672842 @default.
- W2313642483 cites W1994969858 @default.
- W2313642483 cites W1998439215 @default.
- W2313642483 cites W2004652370 @default.
- W2313642483 cites W2005264144 @default.
- W2313642483 cites W2006976038 @default.
- W2313642483 cites W2010721993 @default.
- W2313642483 cites W2011695339 @default.
- W2313642483 cites W2012458244 @default.
- W2313642483 cites W2017476613 @default.
- W2313642483 cites W2018334252 @default.
- W2313642483 cites W2023271753 @default.
- W2313642483 cites W2031812197 @default.
- W2313642483 cites W2031856796 @default.
- W2313642483 cites W2032127435 @default.
- W2313642483 cites W2035300449 @default.
- W2313642483 cites W2046132542 @default.
- W2313642483 cites W2049556135 @default.
- W2313642483 cites W2049784337 @default.
- W2313642483 cites W2052731360 @default.
- W2313642483 cites W2053286315 @default.
- W2313642483 cites W2055429098 @default.
- W2313642483 cites W2064081185 @default.
- W2313642483 cites W2069006374 @default.
- W2313642483 cites W2069513871 @default.
- W2313642483 cites W2069709184 @default.
- W2313642483 cites W2070633066 @default.
- W2313642483 cites W2073582183 @default.
- W2313642483 cites W2083922338 @default.
- W2313642483 cites W2094470462 @default.
- W2313642483 cites W2095416067 @default.
- W2313642483 cites W2117304266 @default.
- W2313642483 cites W2126534793 @default.
- W2313642483 cites W2128329009 @default.
- W2313642483 cites W2131835377 @default.
- W2313642483 cites W2142710291 @default.
- W2313642483 cites W2143981217 @default.
- W2313642483 cites W2152309029 @default.
- W2313642483 cites W2156902602 @default.
- W2313642483 cites W2163866745 @default.
- W2313642483 cites W2240359195 @default.
- W2313642483 cites W36932745 @default.
- W2313642483 cites W3036389375 @default.
- W2313642483 doi "https://doi.org/10.1021/jp109800h" @default.
- W2313642483 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21194192" @default.
- W2313642483 hasPublicationYear "2010" @default.
- W2313642483 type Work @default.
- W2313642483 sameAs 2313642483 @default.
- W2313642483 citedByCount "10" @default.
- W2313642483 countsByYear W23136424832014 @default.
- W2313642483 countsByYear W23136424832015 @default.
- W2313642483 countsByYear W23136424832018 @default.
- W2313642483 countsByYear W23136424832020 @default.
- W2313642483 countsByYear W23136424832021 @default.
- W2313642483 crossrefType "journal-article" @default.
- W2313642483 hasAuthorship W2313642483A5018375399 @default.
- W2313642483 hasAuthorship W2313642483A5038837508 @default.
- W2313642483 hasAuthorship W2313642483A5063132694 @default.
- W2313642483 hasAuthorship W2313642483A5080022083 @default.
- W2313642483 hasAuthorship W2313642483A5085005476 @default.
- W2313642483 hasConcept C104779481 @default.
- W2313642483 hasConcept C113196181 @default.
- W2313642483 hasConcept C121332964 @default.
- W2313642483 hasConcept C139066938 @default.
- W2313642483 hasConcept C140205800 @default.
- W2313642483 hasConcept C147597530 @default.
- W2313642483 hasConcept C152365726 @default.
- W2313642483 hasConcept C159985019 @default.
- W2313642483 hasConcept C161790260 @default.
- W2313642483 hasConcept C178790620 @default.
- W2313642483 hasConcept C184779094 @default.
- W2313642483 hasConcept C185592680 @default.