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- W2313646503 abstract "Bis(alkylimidazole) complexes of zinc, (RIm)2ZnX2, were prepared by a metal insertion reaction. The synthesized (RIm)2ZnX2 exhibited good catalytic performance during synthesis of glycerol carbonate (GC) from glycerol and urea. (HEIm)2ZnCl2 with a hydroxyl group exhibited the highest GC yield during glycerolysis of urea owing to incorporation of acid-base bifunctional active sites. (EIm)2ZnX2 catalysts based on different halide anions showed increased reactivity as Cl- < Br- < I-, which is the order of nucleophilicity. The effects of reaction parameters such as temperature, reaction time, catalyst loading, and degree of vacuum on the reactivity were also investigated." @default.
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- W2313646503 date "2014-06-01" @default.
- W2313646503 modified "2023-09-25" @default.
- W2313646503 title "Organic–Inorganic Hybrids of Imidazole Complexes of Zinc (II) for Catalysts in the Glycerolysis of Urea" @default.
- W2313646503 doi "https://doi.org/10.1166/jnn.2014.8237" @default.
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