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- W2313871760 abstract "ギ酸銅四水和物Cu(HCO2)2・4H20の結晶水を尿素でおきかえたCu(HCO2)2・(NH2CONH2)2・2H20とCu(HCO2)2・(NH2,CONH2)を合成した。酢酸銅の尿素付加物もえられた(2種類)。それらの磁化率をGouyの方法で測定して,銅原子の磁気モ_メントを求めた。Cu(HCO2)2・(NH2CONH2)2・2H20の磁気モーメントは1.67ボーア磁子,Cu(HCOa)2・(NH2CONH2)のモ_メントは1.08B・M・である。酢酸銅の尿素付加物は,酢酸銅一水和物のモーメントとほとんど同じ値のモーメントを示す。ギ酸銅は,四水和物の結晶水のうち2分子が尿素2分子と入れかわっても,四水和物の構造を維持するが,4分子の結晶水全部が尿素1分子でおきかわると,酢酸銅一水和物型の二量体構造をとる。酢酸銅は,どの尿素付加物も一水和物型のこ量体構造を保持する。尿素は,ギ酸銅とも,酢酸銅とも,共通な付加形式の,大気申で安定な,二量体構造の付加物をつくる牲質をもっている。" @default.
- W2313871760 created "2016-06-24" @default.
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- W2313871760 date "1962-01-01" @default.
- W2313871760 modified "2023-10-14" @default.
- W2313871760 title "Subnormal Magnetic Moments of the Addition Compounds of Copper Formate and Acetate with Urea" @default.
- W2313871760 doi "https://doi.org/10.1246/nikkashi1948.83.3_264" @default.
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