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• W2313903554 abstract "The effect of divalent cations (Me: Ca2+ and Mg2+) on the ligand-exchange kinetics of Fe (III) -fulvic acid complex and desferrioxamine B (DFOB) was examined by spectrophotometrically measuring the rate of Fe (III) -DFOB complex formation at the various concentrations of Me found in natural water (0-50 mM) . A kinetic model for ligand-exchange incorporating the effects of Me was also developed. The model includes the following two pathways: (1) a disjunctive pathway where Fe (III) -fulvic acid complex initially dissociates followed by complexation of free Fe (III) by DFOB; and (2) an adjunctive pathway where DFOB directly associates with the Fe (III) -fulvic acid complex followed by dissociation of the ternary complex (DFOB-Fe (III) -fulvic acid) to form Fe (III) -DFOB. The ligand-exchange rates of both pathways were accelerated in the presence of Me. The enhanced rates were well explained by considering the ternary complex formation of Me and Fe (III) -fulvic acid complex." @default.
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• W2313903554 date "2010-01-01" @default.
• W2313903554 modified "2023-10-14" @default.
• W2313903554 title "Effect of Divalent Cations on Ligand-Exchange Kinetics of Fe (III) -Fulvic Acid Complex and Siderophore Desferrioxamine B" @default.
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• W2313903554 doi "https://doi.org/10.2965/jswe.33.131" @default.
• W2313903554 hasPublicationYear "2010" @default.
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