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• W2314034990 startingPage "648" @default.
• W2314034990 abstract "A highly regio- and diastereoselective TMSOTf promoted vinylogous Mannich reaction for the synthesis of chiral quaternary 3-aminooxindole butenolides from 2-silyloxy furans and chiral ketimines is described. The method is found to be very efficient and also provides a facile access to sterically challenging 3-aminooxindole butenolides bearing two quaternary centers in continuation. Further, the versatility of the method is demonstrated by the 1,4-addition of nucleophiles on the sterically congested butenolide substructure." @default.
• W2314034990 created "2016-06-24" @default.
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• W2314034990 creator A5052835413 @default.
• W2314034990 creator A5057702777 @default.
• W2314034990 date "2014-01-17" @default.
• W2314034990 modified "2023-10-17" @default.
• W2314034990 title "Asymmetric Vinylogous Mannich Reaction of Silyloxy Furans with <i>N</i>-<i>tert</i>-Butanesulfinyl Ketimines" @default.
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• W2314034990 doi "https://doi.org/10.1021/ol4037117" @default.
• W2314034990 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24437720" @default.
• W2314034990 hasPublicationYear "2014" @default.
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