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- W2314072106 abstract "Allylic substitution of monomethoxyacetate of 4-cyclopentene-1,3-diol (91% ee) with 4-FC6H4ZnBr (4 equiv) and CuCl (30 mol%) gave anti-SN2′ product, which upon epoxidation with MCPBA afforded α-epoxide stereoselectively. The epoxide was reduced with LiEt3BH, and the resulting alcohol was converted into the targeted amine by using Mitsunobu reactions twice with 3,5-(O2N)2C6H3CO2H and then with phthalimide." @default.
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- W2314072106 date "2011-11-09" @default.
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- W2314072106 title "Synthesis of an Advanced Intermediate toward the hNK-1 Antagonist with the Cyclopentane Core" @default.
- W2314072106 doi "https://doi.org/10.1055/s-0031-1289863" @default.
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