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• W2314116274 abstract "We report the development of a Pd-catalyzed process for the stereospecific cross-coupling of unactivated secondary alkylboron nucleophiles and aryl chlorides. This process tolerates the use of secondary alkylboronic acids and secondary alkyltrifluoroborates and occurs without significant isomerization of the alkyl nucelophile. Optically active secondary alkyltrifluoroborate reagents undergo cross-coupling reactions with stereospecific inversion of configuration using this method." @default.
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• W2314116274 date "2014-09-23" @default.
• W2314116274 modified "2023-10-14" @default.
• W2314116274 title "Stereospecific Pd-Catalyzed Cross-Coupling Reactions of Secondary Alkylboron Nucleophiles and Aryl Chlorides" @default.
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• W2314116274 doi "https://doi.org/10.1021/ja508815w" @default.
• W2314116274 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/4195375" @default.
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