FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2314226317> ?p ?o ?g. }

• W2314226317 endingPage "12234" @default.
• W2314226317 startingPage "12222" @default.
• W2314226317 abstract "This paper describes a method to study the reactivity of neutral clusters at single-collision-like conditions, which enables the determination of absolute numbers for the reaction probability (S) in a collision. A beam of clusters is produced in a laser vaporization source and skimmed and passes a cell with reactive gas, in which the clusters experience one or a few collisions with the gas molecules. The reaction products are detected with laser ionization and mass spectrometry. The depletion of pure clusters and the appearance of products are evaluated with a statistical model providing S for the first, second, etc., molecule adsorbed. The O2 and D2 reactivity of Fen, Con, and Cun has been investigated for clusters in the approximate size range 10−60 atoms. The oxidation of transition metal clusters, here exemplified by Con and Fen, shows a simple S vs n dependence, where S increases almost monotonically as n increases from 10 to 20, while for larger n, S remains high and almost constant; S ≈ 0.7 for both Fen and Con. The low O2 reactivity measured for the small transition metal clusters may be an effect of the products having a short lifetime due to the high exothermicity of the oxidation reaction. For copper clusters there are repeated minima in the O2 reactivity appearing at cluster sizes that are known to have high IP and closed electronic shells. Con is much less reactive toward D2 than O2, and S for D2 on Con exhibits large size to size fluctuations. Cun and small Fen appear unreactive (detection limit S ≈ 0.02) toward D2, whereas the larger Fen (n ≥ 23) react with a low probability." @default.
• W2314226317 created "2016-06-24" @default.
• W2314226317 creator A5024333048 @default.
• W2314226317 creator A5052721934 @default.
• W2314226317 creator A5069983342 @default.
• W2314226317 date "1996-01-01" @default.
• W2314226317 modified "2023-10-02" @default.
• W2314226317 title "Reactivity of Fe<i>_n</i>, Co<i>_n</i>, and Cu<i>_n</i> Clusters with O₂ and D₂ Studied at Single-Collision Conditions" @default.
• W2314226317 cites W104401682 @default.
• W2314226317 cites W10754371 @default.
• W2314226317 cites W116469318 @default.
• W2314226317 cites W1966378156 @default.
• W2314226317 cites W1966624435 @default.
• W2314226317 cites W1966843807 @default.
• W2314226317 cites W1968307836 @default.
• W2314226317 cites W1969151368 @default.
• W2314226317 cites W1970890810 @default.
• W2314226317 cites W1972891567 @default.
• W2314226317 cites W1973806617 @default.
• W2314226317 cites W1976444108 @default.
• W2314226317 cites W1978254018 @default.
• W2314226317 cites W1979349408 @default.
• W2314226317 cites W1979410678 @default.
• W2314226317 cites W1980807995 @default.
• W2314226317 cites W1981914678 @default.
• W2314226317 cites W1983297651 @default.
• W2314226317 cites W1984538564 @default.
• W2314226317 cites W1986574239 @default.
• W2314226317 cites W1989132883 @default.
• W2314226317 cites W1992403735 @default.
• W2314226317 cites W1993641765 @default.
• W2314226317 cites W1997166366 @default.
• W2314226317 cites W1998244160 @default.
• W2314226317 cites W2002911433 @default.
• W2314226317 cites W2003760769 @default.
• W2314226317 cites W2004623596 @default.
• W2314226317 cites W2004945157 @default.
• W2314226317 cites W2006079665 @default.
• W2314226317 cites W2008046111 @default.
• W2314226317 cites W2008672562 @default.
• W2314226317 cites W2014430923 @default.
• W2314226317 cites W2015919585 @default.
• W2314226317 cites W2020601098 @default.
• W2314226317 cites W2020630440 @default.
• W2314226317 cites W2024864429 @default.
• W2314226317 cites W2025347192 @default.
• W2314226317 cites W2028593833 @default.
• W2314226317 cites W2030019237 @default.
• W2314226317 cites W2031031591 @default.
• W2314226317 cites W2033229920 @default.
• W2314226317 cites W2034480035 @default.
• W2314226317 cites W2034766189 @default.
• W2314226317 cites W2035287960 @default.
• W2314226317 cites W2036082801 @default.
• W2314226317 cites W2037527275 @default.
• W2314226317 cites W2038551888 @default.
• W2314226317 cites W2038777374 @default.
• W2314226317 cites W2040735545 @default.
• W2314226317 cites W2040798280 @default.
• W2314226317 cites W2042669865 @default.
• W2314226317 cites W2044836950 @default.
• W2314226317 cites W2045084786 @default.
• W2314226317 cites W2045216963 @default.
• W2314226317 cites W2046269964 @default.
• W2314226317 cites W2053514515 @default.
• W2314226317 cites W2054404180 @default.
• W2314226317 cites W2054918731 @default.
• W2314226317 cites W2055322624 @default.
• W2314226317 cites W2056319595 @default.
• W2314226317 cites W2058497172 @default.
• W2314226317 cites W2060317288 @default.
• W2314226317 cites W2060600384 @default.
• W2314226317 cites W2062082217 @default.
• W2314226317 cites W2064007719 @default.
• W2314226317 cites W2066966873 @default.
• W2314226317 cites W2067388532 @default.
• W2314226317 cites W2068241704 @default.
• W2314226317 cites W2069438435 @default.
• W2314226317 cites W2072991515 @default.
• W2314226317 cites W2078617995 @default.
• W2314226317 cites W2086129929 @default.
• W2314226317 cites W2087555886 @default.
• W2314226317 cites W2088959409 @default.
• W2314226317 cites W2092220969 @default.
• W2314226317 cites W2095307961 @default.
• W2314226317 cites W2096868202 @default.
• W2314226317 cites W2329441124 @default.
• W2314226317 cites W267322968 @default.
• W2314226317 cites W2014390184 @default.
• W2314226317 doi "https://doi.org/10.1021/jp960889z" @default.
• W2314226317 hasPublicationYear "1996" @default.
• W2314226317 type Work @default.
• W2314226317 sameAs 2314226317 @default.
• W2314226317 citedByCount "74" @default.
• W2314226317 countsByYear W23142263172012 @default.
• W2314226317 countsByYear W23142263172013 @default.
• W2314226317 countsByYear W23142263172014 @default.
• W2314226317 countsByYear W23142263172015 @default.

• next