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- W2314263004 abstract "The integrity, chemical identity, packing density, and molecular orientation in SAMs formed by anthracene-substituted alkanethiols (Ant-n) with a variable number of methylene groups (n) in the aliphatic linker on Au(111) and Ag(111) substrates were studied by a combination of several complementary experimental techniques. The Ant-n molecules were found to form well-defined and highly ordered SAMs on these substrates, with very small inclination of the anthracene backbone. In addition, the Ant-n SAMs exhibited odd−even effects, that is, dependence of the molecular orientation and packing density on the length of the aliphatic linker, with the parity of n being the decisive parameter. While the direction (sign) of this odd−even behavior on gold and silver is the same as for SAMs of biphenyl- and terphenyl-substituted alkanethiolates and -alkaneselenolates, suggesting a common reason behind this phenomenon, the presence of a strong substrate−headgroup−C bending potential, the extent of the odd−even effects in the Ant-n films is noticeably smaller than in the latter systems. This behavior can be explained by the additional rotational degree of freedom of the anthracene unit in the case of the Ant-n SAMs due to its nonsymmetrical attachment to the adjacent alkyl linker. This permits the adoption of an almost upright orientation of the aromatic part regardless of the parity of n. The above behavior is an instructive example that even seemingly subtle changes of the molecular structure may have noticeable implications for the properties of the resulting assemblies." @default.
- W2314263004 created "2016-06-24" @default.
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- W2314263004 date "2011-01-21" @default.
- W2314263004 modified "2023-10-03" @default.
- W2314263004 title "Compensation of the Odd−Even Effects in Araliphatic Self-Assembled Monolayers by Nonsymmetric Attachment of the Aromatic Part" @default.
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- W2314263004 cites W1974872096 @default.
- W2314263004 cites W1974948906 @default.
- W2314263004 cites W1977590126 @default.
- W2314263004 cites W1980200036 @default.
- W2314263004 cites W1982328340 @default.
- W2314263004 cites W1982572165 @default.
- W2314263004 cites W1982937359 @default.
- W2314263004 cites W1983904843 @default.
- W2314263004 cites W1986752938 @default.
- W2314263004 cites W1989268166 @default.
- W2314263004 cites W1989362883 @default.
- W2314263004 cites W1989992078 @default.
- W2314263004 cites W1990150155 @default.
- W2314263004 cites W1999262645 @default.
- W2314263004 cites W2004055185 @default.
- W2314263004 cites W2012600300 @default.
- W2314263004 cites W2012904250 @default.
- W2314263004 cites W2013026314 @default.
- W2314263004 cites W2013117374 @default.
- W2314263004 cites W2014661497 @default.
- W2314263004 cites W2018796834 @default.
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- W2314263004 cites W2021875328 @default.
- W2314263004 cites W2023389628 @default.
- W2314263004 cites W2027085921 @default.
- W2314263004 cites W2027828281 @default.
- W2314263004 cites W2030161177 @default.
- W2314263004 cites W2031183081 @default.
- W2314263004 cites W2035136324 @default.
- W2314263004 cites W2036463959 @default.
- W2314263004 cites W2038820537 @default.
- W2314263004 cites W2039244894 @default.
- W2314263004 cites W2041767969 @default.
- W2314263004 cites W2045532248 @default.
- W2314263004 cites W2046158480 @default.
- W2314263004 cites W2047952781 @default.
- W2314263004 cites W2048865889 @default.
- W2314263004 cites W2052637049 @default.
- W2314263004 cites W2052721424 @default.
- W2314263004 cites W2053604728 @default.
- W2314263004 cites W2057437201 @default.
- W2314263004 cites W2059457616 @default.
- W2314263004 cites W2059543240 @default.
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- W2314263004 cites W2063197760 @default.
- W2314263004 cites W2063639037 @default.
- W2314263004 cites W2063952828 @default.
- W2314263004 cites W2065867670 @default.
- W2314263004 cites W2073169684 @default.
- W2314263004 cites W2076536934 @default.
- W2314263004 cites W2078290379 @default.
- W2314263004 cites W2082666954 @default.
- W2314263004 cites W2083000710 @default.
- W2314263004 cites W2090158050 @default.
- W2314263004 cites W2092023884 @default.
- W2314263004 cites W2093826245 @default.
- W2314263004 cites W2094536176 @default.
- W2314263004 cites W2095252287 @default.
- W2314263004 cites W2100694345 @default.
- W2314263004 cites W2104785971 @default.
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- W2314263004 cites W2166081351 @default.
- W2314263004 cites W2166806803 @default.
- W2314263004 cites W2168948830 @default.
- W2314263004 cites W2185386454 @default.
- W2314263004 cites W2312839838 @default.
- W2314263004 cites W4241214195 @default.
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- W2314263004 doi "https://doi.org/10.1021/jp1118647" @default.
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