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• W2314339898 abstract "The synthesis, isolation, and hydrogen-bonding properties of a series of amide-containing silanediols are described, including an enantioenriched silanediol. By incorporation of a 2,4,6-trimethylphenyl (mesityl) group, these functionalized silanediols are isolable by column chromatography and stable in the presence of standard acids (e.g., AcOH) and bases (e.g., NH4OH). NMR spectroscopy and X-ray crystallography provide evidence for the conformational rigidity and binding properties of amido-silanediols based on the parameters (e.g., sterics, hybridization, and ring size of hydrogen bonding) that affect intra- and intermolecular hydrogen bonding. Pyridine binding studies demonstrate that these conformational effects have implications for the existence of single versus multiple modes of hydrogen bonding." @default.
• W2314339898 created "2016-06-24" @default.
• W2314339898 creator A5012339862 @default.
• W2314339898 creator A5012348248 @default.
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• W2314339898 date "2012-09-18" @default.
• W2314339898 modified "2023-10-18" @default.
• W2314339898 title "NMR and X-ray Studies of Hydrogen Bonding for Amide-Containing Silanediols" @default.
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• W2314339898 doi "https://doi.org/10.1021/om300736n" @default.
• W2314339898 hasPublicationYear "2012" @default.
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