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- W2314385807 abstract "Development of various strategies for controllable fabrication of core–shell nanocomposites (CSNs) with highly active photocatalytic performance has been attracting ever-increasing research attention. In particular, control of the ultrathin layer TiO2 shell in constructing CSNs in an aqueous phase is a significant but technologically challenging issue. Here, this paper demonstrates the interface assembly synthesis of CdS nanospheres@TiO2 core–shell photocatalyst via the electrostatic interaction of negatively charged water-stable titania precursor with positively charged CdS nanospheres (CdS NSPs), followed by the formation of the ultrathin-layer TiO2 shell through a facile refluxing process in aqueous phase. The as-formed CdS NSPs@TiO2 core–shell nanohybrid exhibits a high visible-light-driven photoactivity for selective transformation and reduction of heavy metal ions. The ultrathin TiO2 layer coated on CdS NSPs results in excellent light transmission property, enhanced adsorption capacity, and improved transfer of charge carriers and lifespan of photoinduced electron–hole pairs, which would prominently contribute to the significant photoactivity enhancement. It is anticipated that this facile aqueous-phase synthesis strategy could be extended to design a variety of more efficient CSN photocatalysts with controllable morphology toward target applications in diverse photoredox processes." @default.
- W2314385807 created "2016-06-24" @default.
- W2314385807 creator A5026347224 @default.
- W2314385807 creator A5084634014 @default.
- W2314385807 date "2013-11-22" @default.
- W2314385807 modified "2023-10-16" @default.
- W2314385807 title "Ultrathin TiO<sub>2</sub> Layer Coated-CdS Spheres Core–Shell Nanocomposite with Enhanced Visible-Light Photoactivity" @default.
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- W2314385807 doi "https://doi.org/10.1021/am4043068" @default.
- W2314385807 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24245797" @default.
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