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- W2314390673 abstract "Nylon 6 (Ny 6) monofilaments with various draw ratios were dyed in saturated aqueous solution of 1, 4, 5, 8-tetraaminoanthraquinone (4AAQ) at 90°C under various hydrostatic pressures up to 2.5 kbar. Diffusion coefficient (D) of 4AAQ in Ny 6 and activation volume for the diffusion (ΔV_??_), both along the parallel (_??_) and perpendicular (⊥) directions to the drawing axis, were obtained from the dye penetration distance vs. square root of diffusion time relationship and the pressure dependence of D. It was found that D_??_ decreases rapidly with increasing draw ratio, while D⊥ shows a maximum near draw ratio of 1.9 and then decreases rapidly. In the course of drawing, D⊥, persists in being larger than D_??_. In a striking contrast, however, for ΔV_??_, neither a significant change nor anisotropy for the two directions was obtained with increasing draw ratio. The reason for such an insensitive behavior of ΔV_??_ to the drawing was discussed." @default.
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- W2314390673 date "1983-01-01" @default.
- W2314390673 modified "2023-09-23" @default.
- W2314390673 title "ANISOTROPY OF DIFFUSION COEFFICIENT AND ACTIVATION VOLUME FOR THE DIFFUSION OF DYE IN NYLON 6 FILAMENT" @default.
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- W2314390673 doi "https://doi.org/10.2115/fiber.39.t51" @default.
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