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• W2314433876 endingPage "9756" @default.
• W2314433876 startingPage "9748" @default.
• W2314433876 abstract "Digitoxin, a clinically important cardiac trisaccharide, was assembled efficiently from digitoxigenin and 3,4-di-O-tert-butyldiphenylsilyl-d-digitoxosyl o-cyclopropylethynylbenzoate in 9 steps and 52% overall yield via alternate glycosylation and protecting group manipulation. The present synthesis showcases the advantage of the gold(I)-catalyzed glycosylation protocol in the synthesis of glycoconjugates containing acid-labile 2-deoxysugar linkages." @default.
• W2314433876 created "2016-06-24" @default.
• W2314433876 creator A5020331671 @default.
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• W2314433876 date "2011-11-04" @default.
• W2314433876 modified "2023-10-16" @default.
• W2314433876 title "Assembly of Digitoxin by Gold(I)-Catalyzed Glycosidation of Glycosyl <i>o</i>-Alkynylbenzoates" @default.
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• W2314433876 doi "https://doi.org/10.1021/jo201850z" @default.
• W2314433876 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22054226" @default.
• W2314433876 hasPublicationYear "2011" @default.
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