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- W2314472514 endingPage "4888" @default.
- W2314472514 startingPage "4885" @default.
- W2314472514 abstract "Computational and experimental results demonstrate that adamantanylidene (1) behaves as a highly reactive nucleophile toward common alkenes. It is the only known saturated nucleophilic carbene that lacks direct or vinylogous heteroatomic substitution. The activation energy and enthalpy for addition of 1 to methyl acrylate are the most negative values yet encountered in any carbene–alkene addition." @default.
- W2314472514 created "2016-06-24" @default.
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- W2314472514 date "2014-03-20" @default.
- W2314472514 modified "2023-09-30" @default.
- W2314472514 title "The Nucleophilicity of a Dialkylcarbene: Unusual Activation Parameters for Additions of Adamantanylidene to Simple Alkenes" @default.
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- W2314472514 doi "https://doi.org/10.1021/ja501410x" @default.
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