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• W2314496492 abstract "Spinel Li4Ti5O12 (LTO) and reduced graphene oxide (rGO) are attractive anode materials for lithium-ion batteries (LIBs) because of their unique electrochemical properties. Herein, we report a facile one-step hydrothermal method in preparation of a nanocomposite anode consisting of well-dispersed mesoporous LTO particles onto rGO. An important reaction step involves glucose as a novel linker agent and reducing agent during the synthesis. It was found to prevent the aggregation of LTO particles, and to yield mesoporous structures in nanocomposites. Moreover, GO is reduced to rGO by the hydroxyl groups on glucose during the hydrothermal process. When compared to previously reported LTO/graphene electrodes, the newly prepared LTO/rGO nanocomposite has mesoporous characteristics and provides additional surface lithium storage capability, superior to traditional LTO-based materials for LIBs. These unique properties lead to markedly improved electrochemical performance. In particular, the nanocomposite anode delivers an ultrahigh reversible capacity of 193 mA h g–1 at 0.5 C and superior rate performance capable of retaining a capacity of 168 mA h g–1 at 30 C between 1.0 and 2.5 V. Therefore, the newly prepared mesoporous LTO/rGO nanocomposite with increased surface lithium storage capability will provide a new opportunity to develop high-power anode materials for LIBs." @default.
• W2314496492 created "2016-06-24" @default.
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• W2314496492 date "2016-03-31" @default.
• W2314496492 modified "2023-10-17" @default.
• W2314496492 title "Advanced Mesoporous Spinel Li₄Ti₅O₁₂/rGO Composites with Increased Surface Lithium Storage Capability for High-Power Lithium-Ion Batteries" @default.
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• W2314496492 doi "https://doi.org/10.1021/acsami.6b01644" @default.
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• W2314496492 hasPublicationYear "2016" @default.
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