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- W2314511115 abstract "The trans/gauche ratio for 1,2-dichloroethane was determined at 2980K from the respective infrared absorptions of the two conformations using FTIR techniques. From measurements in twelve aprotic solvents, it was determined that the ratio decreases as the solvent polarity increases in aprotic dipolar media. This solvent-dependent trend was analyzed in terms of the conformational free energy shift (AGo) arising from the coupling of dipolarity and polarizability factors within the reaction field. Of the several reaction field models examined, the McRae function proved to be superior in correlating the AGO data with solvent dielectric constant (E) and index of refraction (n) parameters." @default.
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- W2314511115 date "1998-01-01" @default.
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- W2314511115 title "Solvent Reaction Field Effects upon the Trans/Gauche Conformational Equilibrium of 1,2-Dichloroethane in Aprotic Media" @default.
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- W2314511115 doi "https://doi.org/10.2307/3627955" @default.
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