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• W2314590157 abstract "We have studied the collision energy dependent cross section and alignment of NO (A 2Σ+) rotation in the energy-transfer reaction of N2 (A 3Σu+) + NO (X 2Π) → N2 (X 1Σg+) + NO (A 2Σ+) at the collision energy (E) region of 0.03–0.2 eV. NO (A 2Σ+) emission in two linear polarization directions in the collision frame (parallel (∥) and perpendicular (⊥) with respect to the relative velocity vector (vR)) has been measured as a function of collision energy. NO (A 2Σ+) rotation (J-vector) turns out to be aligned perpendicular to vR. In addition, collision energy is found to enhance the degree of alignment of NO (A 2Σ+) rotation. The collision energy dependent cross sections σ∥,(⊥)(E) (excitation functions) show a rapid fall-off following an initial rise with a threshold less than 0.02 eV. The excitation function at the parallel alignment of NO (A 2Σ+) rotation, σ(J∥vR, (E), is slightly shifted to the low collision energy region as compared with σ(J ⊥ vR, E). We propose that the rapid fall-off feature in the excitation function is attributed to the multidimensional nonadiabatic transitions." @default.
• W2314590157 created "2016-06-24" @default.
• W2314590157 creator A5090877632 @default.
• W2314590157 date "2014-10-02" @default.
• W2314590157 modified "2023-09-25" @default.
• W2314590157 title "Collision Energy Dependent Cross Section and Rotational Alignment of NO (A ²Σ⁺) in the Energy-Transfer Reaction of N₂ (A³Σ_u⁺) + NO (X ²Π) → N₂ (X ¹Σ_g⁺) + NO (A ²Σ⁺)" @default.
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• W2314590157 doi "https://doi.org/10.1021/jp507696y" @default.
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• W2314590157 hasPublicationYear "2014" @default.
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