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- W2314678507 abstract "The addition of ynamides to acyl chlorides and N-heterocycles activated in situ with ethyl chloroformate has been accomplished at room temperature using copper iodide as catalyst. This economical and practical carbon–carbon bond formation provides convenient access to a variety of 3-aminoynones from aliphatic and aromatic acyl chlorides in up to 99% yield. The addition to pyridines and quinolines occurs under almost identical conditions and proceeds with good to high regioselectivity, producing the corresponding 1,2-dihydro-N-heterocycles in up to 95% yield." @default.
- W2314678507 created "2016-06-24" @default.
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- W2314678507 date "2014-04-18" @default.
- W2314678507 modified "2023-09-26" @default.
- W2314678507 title "Copper(I)-Catalyzed Nucleophilic Addition of Ynamides to Acyl Chlorides and Activated <i>N</i>-Heterocycles" @default.
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- W2314678507 doi "https://doi.org/10.1021/jo500365h" @default.
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