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- W2314795897 abstract "Ion exchange of ionic semiconductor nanoparticles (NPs) is a facile method for the synthesis of type-II semiconductor heterostructured NPs with staggered alignment of band edges for photoelectric applications. Through consideration of the crystallographic orientation and strain at the heterointerface, well-designed heterostructures can be constructed through ion exchange reactions. Here we report the selective synthesis of anisotropically phase-segregated cadmium sulfide (CdS)/ cadmium telluride (CdTe) heterodimers via a novel anion exchange reaction of CdS NPs with an organic telluride precursor. The wurtzite-CdS/zinc blende-CdTe heterodimers in this study resulted from spontaneous phase segregation induced by the differences in the crystal structures of the two phases, accompanying a centrosymmetry breaking of the spherical CdS NPs. The CdS/CdTe heterodimers exhibited photoinduced spatial charge separation because of their staggered band-edge alignment." @default.
- W2314795897 created "2016-06-24" @default.
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- W2314795897 date "2011-10-13" @default.
- W2314795897 modified "2023-09-28" @default.
- W2314795897 title "Spontaneous Formation of Wurzite-CdS/Zinc Blende-CdTe Heterodimers through a Partial Anion Exchange Reaction" @default.
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- W2314795897 doi "https://doi.org/10.1021/ja2078224" @default.
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