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- W2314882136 abstract "Abstract The speeds of sound has been obtained at a frequency of 4 MHz in diethylene glycol dimethyl ether + methanol, + ethanol, + 1-butanol, and + 1-pentanol across the entire composition range, at the temperature 298.15 K and atmospheric pressure using a NUSONIC velocimeter based on the sing-around technique. The ultrasonic speed values have been combined with those of the excess molar volumes converted to densities to obtain estimates of the product K S,m of the molar volumes and isentropic compressibility κ S , and excess quantity K E S,m . The K E S,m values are negative over the entire range of composition for all mixtures with the exception of 1-pentanol, which changes sign from positive to negative. The magnitude of K E S,m increase with the number of carbon atoms in the n-alcohol. The deviations of the speeds of sound u D from their ideal values u id in an ideal mixture were also calculated for all measured mole fractions. The behaviour of u, u D , and K E S,m with composition and the number of carbon atoms in the alcohol molecule is discussed." @default.
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- W2314882136 date "2001-01-01" @default.
- W2314882136 modified "2023-09-23" @default.
- W2314882136 title "Speeds of Sound and Isentropic Compressibilities of Diethylene Glycol Dimethyl Ether - n-Alcohol Mixtures at 298.15 K" @default.
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- W2314882136 doi "https://doi.org/10.1524/zpch.2001.215.1.091" @default.
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