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- W2314888959 abstract "Thermal and photochemical syntheses of aryl derivatives with highly aliphatic chains were examined and the following results were obtained.1) The thermal reaction of decene-mercuric acetate adduct with benzene affords 1-phenyl-2-decene (yield 18.7%) as the main product, while the photochemical reaction affords 1-phenyl-1-decene (3.6%), 1-phenyl-2-decene (11.3%), 1-phenyl-3-decene (2.6%) and 1-phenyl-4-decene (1.6%).2) The thermal reaction of decene-mercuric acetate adduct with toluene affords 1- (2-methylphenyl) -2-decene (18.0%) and 1- (4-methyl-phenyl) -2-decene (23.5%) as main products, while the photochemical reaction gives 1- (3-methylphenyl) -decane (22.8%) and 1- (4-methylphenyl) -decane (31.3%).3) These products would be formed through heterolytic cleavage of aryl- (acetoxymercury) -decane with demercuration in the thermal process, while through homolytic cleavage in the photochemical process." @default.
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- W2314888959 date "1971-01-01" @default.
- W2314888959 modified "2023-10-16" @default.
- W2314888959 title "Syntheses of Aryl Derivatives by Thermal and Photochemical Reactions of Decene-Mercuric acetate Adducts in Aromatic Solvents. (I)" @default.
- W2314888959 cites W1963739461 @default.
- W2314888959 doi "https://doi.org/10.5650/jos1956.20.415" @default.
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