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• W2314902562 startingPage "627" @default.
• W2314902562 abstract "Addition of 3 molar equiv of AlMe3 to (Me5C5)2Yb(ER)(NH3) gives two types of products depending on the identity of the ER group. When ER is OSiMe3 or TePh, the isolated metallocene is [(Me5C5)2Yb(Me4Al)]2, which exists as an equilibrium between monomeric and dimeric forms in toluene solution. When ER is OCMe3, SPh, S-p-tolyl, or SePh, the isolated metallocenes have the stoichiometry (Me5C5)2Yb(ER)(Me3Al)2. The 1H NMR spectra of these molecules show that several species are present in solution. The crystal structure of the S-p-tolyl derivative shows that two (Me5C5)2Yb fragments are bridged by two Me3Al(S-p-tolyl)AlMe3 units by way of nearly linear Yb···H3C−Al bonds." @default.
• W2314902562 created "2016-06-24" @default.
• W2314902562 creator A5019245331 @default.
• W2314902562 creator A5035244196 @default.
• W2314902562 date "2003-01-17" @default.
• W2314902562 modified "2023-09-24" @default.
• W2314902562 title "Reaction of (C₅Me₅)₂Yb(ER)(NH₃) with Me₃Al. Formation of (C₅Me₅)₂Yb(AlMe₄) and [(C₅Me₅)₂Yb(ER)(AlMe₃)₂]₂" @default.
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• W2314902562 doi "https://doi.org/10.1021/om020472h" @default.
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