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- W2314975099 abstract "To confirm whether the activity trends in multistep organic reactions can be understood in terms of the Hammer–Nørskov d-band model in combination with the linear energy relations, we studied correlations between the reaction rates for dehydrogenation and hydrogenation reactions and the position of the d-band center (εd) relative to the Fermi energy (EF), the εd – EF value, of various metal catalysts. SiO2-supported metal (M = Ag, Cu, Pt, Ir, Pd, Rh, Ru, Ni, and Co) catalysts with the same metal loading (5 wt %) and similar metal particle size (8.9–11.7 nm) were prepared. The dehydrogenation of adsorbed 2-propanol in a flow of He and the hydrogenation of adsorbed nitrobenzene in a flow of H2 were tested as model reactions of organic reactions on the metal surface. As a test reaction of H2 dissociation on the surface, SiOH/SiOD exchange on the M/SiO2 catalysts in a flow of D2 is carried out. The liquid phase hydrogenation of nitrobenzene under 3.0 MPa of H2 is adopted as an organic reaction under realistic conditions. Generally, the activities show volcano-type dependences on the εd – EF value, indicating that the εd – EF value is useful as a qualitative activity descriptor in heterogeneous catalysis of metal nanoparticles for multistep organic reactions." @default.
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- W2314975099 date "2012-08-07" @default.
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- W2314975099 title "Volcano-Curves for Dehydrogenation of 2-Propanol and Hydrogenation of Nitrobenzene by SiO<sub>2</sub>-Supported Metal Nanoparticles Catalysts As Described in Terms of a d-Band Model" @default.
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- W2314975099 doi "https://doi.org/10.1021/cs300376u" @default.
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