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W2314996835 abstract "Magnetic circular dichroism (MCD) and electronic absorption spectroscopies have been used to probe the electronic structure of the classical paramagnetic metal–metal-bonded complexes [Re2X4(PMe3)4]+ (X = Cl, Br). A violation of the MCD sum rule is observed that indicates the presence of ground-state contributions to the MCD intensity. The z-polarized δ → δ* band in the near-IR is formally forbidden in MCD but gains intensity through a combination of ground- and excited-state mechanisms to yield a positive C term." @default.
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W2314996835 date "2014-01-17" @default.
W2314996835 modified "2023-09-23" @default.
W2314996835 title "Magnetic Circular Dichroism and Electronic Structure of [Re2X4(PMe3)4]+ (X = Cl, Br)" @default.
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W2314996835 doi "https://doi.org/10.1021/ic4028139" @default.
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