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- W2315066738 abstract "Treatment of phenyltrichlorosilane with an excess of morpholine and N-lithium-morpholide in pentane/toluene affords only the disubstitution product Cl(Ph)Si(Mor) 2 with Mor = O(CH 2 CH 2 ) 2 N-. The third halogen atom is not replaced owing to sterical hindrance. The title compound crystallizes with two independent molecules in the unit cell. These two molecules can be classified as enantiomers, because a disrotatory twist of the two morpholino ligands away from the potential mirror plane induces a chiral conformation. In benzene solution there is racemization owing to completely free rotation, chair/boat interconversion, and nitrogen inversion of the morpholino groups on the NMR time scale, but all CH 2 protons remain anisochronous (diastereotopic)." @default.
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- W2315066738 date "1999-01-01" @default.
- W2315066738 modified "2023-10-17" @default.
- W2315066738 title "The Stereochemistry of Chloro-bis(N-morpholino)phenylsilane" @default.
- W2315066738 doi "https://doi.org/10.1515/znb-1999-0106" @default.
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