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• W2315153719 endingPage "6513" @default.
• W2315153719 startingPage "6510" @default.
• W2315153719 abstract "When isomers of the dibridgehead diphosphine P((CH2)14)3P (2) are treated with Me2SAuCl, 2·(AuCl)2 is obtained in high yields. With in,in-/out,out-2 (97:3 equilibrium mixture), only a single isomer can be detected by low-temperature NMR, which is assigned as out,out-2·(AuCl)2 on the basis of the crystal structure. With in,out-2, in,out-2·(AuCl)2 is obtained, as confirmed by a crystal structure. Both lattices show hydrogen bonding between the AuCl moieties of one molecule and the PCH2 hydrogen atoms of a neighboring molecule. This requires access to the backside of the P–Au–Cl linkages, distorting the diphosphine cages. When out,out-2·(AuCl)2 is treated with CH3Li, out,out-2·(AuCH3)2 can be isolated (91%). Analogous hydrogen bonding is impossible, and this molecule crystallizes with a much more symmetrical cage, the center of which is occupied by a methylcyclopentane solvate." @default.
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• W2315153719 date "2011-11-28" @default.
• W2315153719 modified "2023-09-26" @default.
• W2315153719 title "Syntheses and Structures of Digold Complexes of Macrobicyclic Dibridgehead Diphosphines That Can Turn Themselves Inside Out" @default.
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• W2315153719 doi "https://doi.org/10.1021/om200924g" @default.
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