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• W2315205370 abstract "The first examples of the asymmetric synthesis of P-stereogenic vinylic phospholene boranes are described. The synthetic approach is concise and flexible. The route involves (i) asymmetric deprotonation–allylation of a dimethyl phosphine borane; (ii) telescoped regioselective deprotonation, paraformaldehyde trapping, and hydroxyl group elimination to give a diene; and (iii) ring-closing metathesis." @default.
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• W2315205370 date "2012-12-21" @default.
• W2315205370 modified "2023-09-28" @default.
• W2315205370 title "Synthesis of <i>P</i>-Stereogenic Phospholene Boranes via Asymmetric Deprotonation and Ring-Closing Metathesis" @default.
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• W2315205370 doi "https://doi.org/10.1021/ol303253h" @default.
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• W2315205370 hasPublicationYear "2012" @default.
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