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- W2315236087 abstract "We describe the facile atom-efficient synthesis of diblock copolymer nano-objects via a one-pot RAFT aqueous dispersion polymerization protocol starting from a water-immiscible methacrylic monomer. More specifically, an aqueous emulsion of glycidyl methacrylate (GlyMA) is quantitatively converted into a 10% w/w aqueous solution of glycerol monomethacrylate (GMA) at 80 °C in air within 9 h in deionized water. 1H NMR spectroscopy studies indicate no evidence for either methacrylic ester hydrolysis or polymerization during this ring-opening reaction. Kinetic analysis indicates that a significant rate acceleration occurs as the reaction mixture switches from a two-phase emulsion to a single aqueous phase. This observation is fully consistent with the GlyMA–GMA–water ternary phase diagram determined at 80 °C. The 10% w/w aqueous solution of GMA can be polymerized using RAFT chemistry to produce a near-monodisperse PGMA macromolecular chain-transfer agent (macro-CTA), which indicates that relatively little dime..." @default.
- W2315236087 created "2016-06-24" @default.
- W2315236087 creator A5047595253 @default.
- W2315236087 creator A5069717843 @default.
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- W2315236087 date "2013-01-17" @default.
- W2315236087 modified "2023-09-27" @default.
- W2315236087 title "From a Water-Immiscible Monomer to Block Copolymer Nano-Objects via a One-Pot RAFT Aqueous Dispersion Polymerization Formulation" @default.
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- W2315236087 doi "https://doi.org/10.1021/ma301909w" @default.
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