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- W2315273463 abstract "An efficient nitration of silyl allenes with nitrogen dioxide radical, generated from NaNO2 and AcOH, to form α-nitro-α,β-unsaturated silyl oximes has been developed. A similar nitration could be achieved by using Fe(NO3)3·9H2O and FeCl3·6H2O, but different from the regioselective oxime formation, two regioisomeric chloride-trapped products were isolated with varying ratios depending on the steric bulk of the silyl group. A novel ring-closure reaction of α-nitro-α,β-unsaturated silyl oximes upon treating with TBAF to form isooxazolidinone derivatives was also developed." @default.
- W2315273463 created "2016-06-24" @default.
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- W2315273463 date "2013-07-22" @default.
- W2315273463 modified "2023-10-06" @default.
- W2315273463 title "Nitration of Silyl Allenes To Form Functionalized Nitroalkenes" @default.
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- W2315273463 doi "https://doi.org/10.1021/ol401735v" @default.
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