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- W2315341503 abstract "The first Pd-catalyzed enantioselective [2,3]-rearrangement of allylic amine N-oxides is described, which formally represents an asymmetric Meisenheimer rearrangement. The mild reaction conditions enable the synthesis of chiral nonracemic aliphatic allylic alcohol derivatives with reactive functional groups. On the basis of preliminary studies, a cyclization-mediated mechanism is proposed." @default.
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- W2315341503 date "2011-01-10" @default.
- W2315341503 modified "2023-09-26" @default.
- W2315341503 title "Catalytic Enantioselective [2,3]-Rearrangements of Amine <i>N</i>-Oxides" @default.
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- W2315341503 doi "https://doi.org/10.1021/ja110500m" @default.
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